# electronic Ligand Builder and Optimisation Workbench (eLBOW)
#   - a module of PHENIX version dev-svn-
#   - file written: Thu Aug  4 22:30:00 2022
#   Inital geometry file: a 128 line input string
#   Ligand name: ethyl (8R)-7-methyl-3-({[(4-sulfamoylphenyl)methyl]carbamothioyl}amino)pyrazolo[1,5-a]pyrimidine-6-carboxylate
#   Quantum optimisation: True
#   Method: PBEh-3c
#   Random seed: 3628800
#   SMILES string: CCOC(=O)c1cnc2n(ncc2NC(=S)NCc3ccc(cc3)[S](N)(=O)=O)c1C
#
data_comp_list
loop_
_chem_comp.id
_chem_comp.three_letter_code
_chem_comp.name
_chem_comp.group
_chem_comp.number_atoms_all
_chem_comp.number_atoms_nh
_chem_comp.desc_level
_chem_comp.initial_date
_chem_comp.modified_date
_chem_comp.source
 ZOA  ZOA  "ethyl (8R)-7-methyl-3-({[(4-sulfamoylphenyl)methyl]carbamothioyl}amino)pyrazolo[1,5-a]pyrimidine-6-carboxylate"  ligand  50  30  .  2022-08-11  2022-09-22
;
Directly from eLBOW using geometry from QM method PBEh-3c with CPCM solvent model
Validated by Mogul as OK
;

data_comp_ZOA
loop_
_chem_comp_atom.comp_id
_chem_comp_atom.atom_id
_chem_comp_atom.type_symbol
_chem_comp_atom.type_energy
_chem_comp_atom.charge
_chem_comp_atom.partial_charge
_chem_comp_atom.x
_chem_comp_atom.y
_chem_comp_atom.z
 ZOA  C17  C  CR6   0   0.140  16.2506   5.2300  15.5410
 ZOA  C20  C  CR6   0  -0.215  16.0550   2.4684  15.6994
 ZOA  C26  C  CR16  0  -0.273  15.0305   4.5958  15.3201
 ZOA  C28  C  CR15  0   0.012  13.7163   7.7061  10.4465
 ZOA  C02  C  CR6   0   0.476  13.1761  10.7958   9.0827
 ZOA  C03  C  CR6   0  -0.275  13.8780  11.9485   9.3639
 ZOA  C04  C  C     0   0.570  13.6111  13.2150   8.6397
 ZOA  O05  O  O2    0  -0.457  13.9692  14.2643   9.3588
 ZOA  C06  C  CH2   0  -0.179  13.8592  15.5677   8.7601
 ZOA  C07  C  CH3   0  -0.686  14.3948  16.5732   9.7490
 ZOA  O08  O  O     0  -0.434  13.1477  13.2856   7.5282
 ZOA  C09  C  CR16  0  -0.037  14.9164  11.9012  10.3384
 ZOA  N10  N  N     0  -0.410  15.2799  10.8268  10.9747
 ZOA  C11  C  CR56  0   0.598  14.6068   9.7071  10.6842
 ZOA  C12  C  CR5   0  -0.020  14.7138   8.4044  11.1360
 ZOA  N13  N  NH1   0  -0.721  15.6460   7.9138  12.0505
 ZOA  C14  C  C     0   0.402  15.3706   7.6462  13.3472
 ZOA  N15  N  NH1   0  -0.602  16.4024   7.1607  14.0461
 ZOA  C16  C  CH2   0  -0.392  16.3636   6.7296  15.4260
 ZOA  C18  C  CR16  0  -0.289  17.3696   4.4587  15.8421
 ZOA  C19  C  CR16  0  -0.208  17.2817   3.0780  15.9204
 ZOA  S21  S  S     0   1.361  15.9324   0.7048  15.8132
 ZOA  O22  O  OS    0  -0.646  14.5271   0.3722  16.0006
 ZOA  N23  N  NC2   0  -0.889  16.5059   0.2503  14.3298
 ZOA  O24  O  OS    0  -0.660  16.8996   0.2092  16.7812
 ZOA  C25  C  CR16  0  -0.220  14.9244   3.2172  15.4027
 ZOA  S27  S  S1    0  -0.413  13.8484   7.9265  14.0040
 ZOA  N29  N  N     0  -0.290  13.0275   8.4784   9.6280
 ZOA  N30  N  N     0  -0.417  13.5726   9.6928   9.7663
 ZOA  H1   H  HCR6  0   0.264  14.1538   5.1876  15.0881
 ZOA  H2   H  HCR5  0   0.290  13.4776   6.6561  10.5280
 ZOA  H3   H  HCH3  0   0.275  11.2725   9.9882   8.6180
 ZOA  H4   H  HCH3  0   0.279  11.5872  11.5613   7.8679
 ZOA  H5   H  HCH3  0   0.283  12.3628  10.1044   7.2489
 ZOA  H6   H  HCH2  0   0.240  14.4285  15.5912   7.8291
 ZOA  H7   H  HCH2  0   0.239  12.8132  15.7692   8.5220
 ZOA  H8   H  HCH3  0   0.241  14.3170  17.5710   9.3184
 ZOA  H9   H  HCH3  0   0.238  13.8257  16.5655  10.6783
 ZOA  H10  H  HCH3  0   0.238  15.4440  16.3895   9.9795
 ZOA  H11  H  HCR6  0   0.284  15.4657  12.8052  10.5710
 ZOA  H12  H  HNH1  0   0.409  16.5850   7.7560  11.7100
 ZOA  H13  H  HNH1  0   0.408  17.2725   6.9879  13.5617
 ZOA  H14  H  HCH2  0   0.282  17.2761   7.0751  15.9126
 ZOA  H15  H  HCH2  0   0.276  15.5210   7.2186  15.9117
 ZOA  H16  H  HCR6  0   0.269  18.3232   4.9404  16.0204
 ZOA  H17  H  HCR6  0   0.283  18.1613   2.4937  16.1554
 ZOA  H18  H  HNC2  0   0.417  16.8057  -0.7205  14.3278
 ZOA  H19  H  HNC2  0   0.414  15.8383   0.4152  13.5827
 ZOA  H20  H  HCR6  0   0.281  13.9674   2.7406  15.2414
 ZOA  C01  C  CH3   0  -0.734  12.0303  10.6165   8.1541

loop_
_chem_comp_bond.comp_id
_chem_comp_bond.atom_id_1
_chem_comp_bond.atom_id_2
_chem_comp_bond.type
_chem_comp_bond.value_dist
_chem_comp_bond.value_dist_esd
_chem_comp_bond.value_dist_neutron
 ZOA  C01  C02  single    1.486  0.020  1.486
 ZOA  O08  C04  double    1.206  0.020  1.206
 ZOA  N29  N30  aromatic  1.338  0.020  1.338
 ZOA  N29  C28  aromatic  1.319  0.020  1.319
 ZOA  C02  N30  aromatic  1.357  0.020  1.357
 ZOA  C02  C03  aromatic  1.379  0.020  1.379
 ZOA  C04  C03  single    1.483  0.020  1.483
 ZOA  C04  O05  single    1.322  0.020  1.322
 ZOA  N30  C11  aromatic  1.383  0.020  1.383
 ZOA  C28  C12  aromatic  1.399  0.020  1.399
 ZOA  C03  C09  aromatic  1.425  0.020  1.425
 ZOA  C06  O05  single    1.439  0.020  1.439
 ZOA  C06  C07  single    1.509  0.020  1.509
 ZOA  C11  C12  aromatic  1.383  0.020  1.383
 ZOA  C11  N10  aromatic  1.338  0.020  1.338
 ZOA  C12  N13  single    1.395  0.020  1.395
 ZOA  C09  N10  aromatic  1.300  0.020  1.300
 ZOA  N13  C14  single    1.352  0.020  1.352
 ZOA  C14  N15  single    1.337  0.020  1.337
 ZOA  C14  S27  double    1.681  0.020  1.681
 ZOA  N15  C16  single    1.446  0.020  1.446
 ZOA  C16  C17  single    1.508  0.020  1.508
 ZOA  C17  C18  aromatic  1.392  0.020  1.392
 ZOA  C17  C26  aromatic  1.393  0.020  1.393
 ZOA  C18  C19  aromatic  1.386  0.020  1.386
 ZOA  C26  C25  aromatic  1.385  0.020  1.385
 ZOA  C19  C20  aromatic  1.388  0.020  1.388
 ZOA  C25  C20  aromatic  1.388  0.020  1.388
 ZOA  N23  S21  single    1.654  0.020  1.654
 ZOA  C20  S21  single    1.772  0.020  1.772
 ZOA  O22  S21  double    1.456  0.020  1.456
 ZOA  S21  O24  double    1.455  0.020  1.455
 ZOA  C26  H1   single    0.930  0.020  1.080
 ZOA  C28  H2   single    0.930  0.020  1.080
 ZOA  C01  H3   single    0.970  0.020  1.090
 ZOA  C01  H4   single    0.970  0.020  1.090
 ZOA  C01  H5   single    0.970  0.020  1.090
 ZOA  C06  H6   single    0.970  0.020  1.090
 ZOA  C06  H7   single    0.970  0.020  1.090
 ZOA  C07  H8   single    0.970  0.020  1.090
 ZOA  C07  H9   single    0.970  0.020  1.090
 ZOA  C07  H10  single    0.970  0.020  1.090
 ZOA  C09  H11  single    0.930  0.020  1.080
 ZOA  N13  H12  single    0.860  0.020  1.020
 ZOA  N15  H13  single    0.860  0.020  1.020
 ZOA  C16  H14  single    0.970  0.020  1.090
 ZOA  C16  H15  single    0.970  0.020  1.090
 ZOA  C18  H16  single    0.930  0.020  1.080
 ZOA  C19  H17  single    0.930  0.020  1.080
 ZOA  N23  H18  single    0.890  0.020  1.040
 ZOA  N23  H19  single    0.890  0.020  1.040
 ZOA  C25  H20  single    0.930  0.020  1.080

loop_
_chem_comp_angle.comp_id
_chem_comp_angle.atom_id_1
_chem_comp_angle.atom_id_2
_chem_comp_angle.atom_id_3
_chem_comp_angle.value_angle
_chem_comp_angle.value_angle_esd
 ZOA  C18  C17  C16  120.48  3.000
 ZOA  C18  C17  C26  119.09  3.000
 ZOA  C16  C17  C26  120.41  3.000
 ZOA  C25  C20  S21  119.63  3.000
 ZOA  S21  C20  C19  119.23  3.000
 ZOA  C25  C20  C19  121.14  3.000
 ZOA  H1   C26  C25  119.65  3.000
 ZOA  H1   C26  C17  119.63  3.000
 ZOA  C25  C26  C17  120.72  3.000
 ZOA  H2   C28  N29  120.03  3.000
 ZOA  H2   C28  C12  127.28  3.000
 ZOA  N29  C28  C12  112.69  3.000
 ZOA  N30  C02  C03  115.35  3.000
 ZOA  C03  C02  C01  128.40  3.000
 ZOA  N30  C02  C01  116.24  3.000
 ZOA  C09  C03  C04  119.57  3.000
 ZOA  C09  C03  C02  118.87  3.000
 ZOA  C04  C03  C02  121.52  3.000
 ZOA  O08  C04  O05  123.99  3.000
 ZOA  O05  C04  C03  111.32  3.000
 ZOA  O08  C04  C03  124.69  3.000
 ZOA  C06  O05  C04  118.18  3.000
 ZOA  H7   C06  H6   108.05  3.000
 ZOA  H7   C06  C07  111.11  3.000
 ZOA  H6   C06  C07  111.07  3.000
 ZOA  H7   C06  O05  109.35  3.000
 ZOA  H6   C06  O05  109.54  3.000
 ZOA  C07  C06  O05  107.69  3.000
 ZOA  H10  C07  H9   108.73  3.000
 ZOA  H10  C07  H8   107.86  3.000
 ZOA  H9   C07  H8   107.83  3.000
 ZOA  H10  C07  C06  111.60  3.000
 ZOA  H9   C07  C06  111.65  3.000
 ZOA  H8   C07  C06  109.03  3.000
 ZOA  H11  C09  N10  116.27  3.000
 ZOA  H11  C09  C03  119.26  3.000
 ZOA  N10  C09  C03  124.46  3.000
 ZOA  C11  N10  C09  116.38  3.000
 ZOA  N30  C11  C12  105.36  3.000
 ZOA  C12  C11  N10  132.71  3.000
 ZOA  N30  C11  N10  121.93  3.000
 ZOA  N13  C12  C11  126.66  3.000
 ZOA  N13  C12  C28  128.60  3.000
 ZOA  C11  C12  C28  104.71  3.000
 ZOA  H12  N13  C14  118.75  3.000
 ZOA  H12  N13  C12  117.05  3.000
 ZOA  C14  N13  C12  124.20  3.000
 ZOA  S27  C14  N15  123.70  3.000
 ZOA  S27  C14  N13  121.73  3.000
 ZOA  N15  C14  N13  114.57  3.000
 ZOA  H13  N15  C16  115.44  3.000
 ZOA  H13  N15  C14  118.40  3.000
 ZOA  C16  N15  C14  125.88  3.000
 ZOA  H15  C16  H14  107.84  3.000
 ZOA  H15  C16  N15  108.21  3.000
 ZOA  H14  C16  N15  107.99  3.000
 ZOA  H15  C16  C17  110.78  3.000
 ZOA  H14  C16  C17  110.10  3.000
 ZOA  N15  C16  C17  111.79  3.000
 ZOA  H16  C18  C19  119.32  3.000
 ZOA  H16  C18  C17  119.79  3.000
 ZOA  C19  C18  C17  120.89  3.000
 ZOA  H17  C19  C18  119.93  3.000
 ZOA  H17  C19  C20  121.07  3.000
 ZOA  C18  C19  C20  119.00  3.000
 ZOA  O24  S21  N23  105.81  3.000
 ZOA  O24  S21  O22  118.56  3.000
 ZOA  N23  S21  O22  112.78  3.000
 ZOA  O24  S21  C20  109.62  3.000
 ZOA  O22  S21  C20  107.60  3.000
 ZOA  N23  S21  C20  101.06  3.000
 ZOA  H19  N23  H18  110.35  3.000
 ZOA  H19  N23  S21  112.78  3.000
 ZOA  H18  N23  S21  111.50  3.000
 ZOA  H20  C25  C26  119.84  3.000
 ZOA  H20  C25  C20  121.00  3.000
 ZOA  C26  C25  C20  119.16  3.000
 ZOA  N30  N29  C28  104.74  3.000
 ZOA  N29  N30  C11  112.49  3.000
 ZOA  C11  N30  C02  122.99  3.000
 ZOA  N29  N30  C02  124.51  3.000
 ZOA  H5   C01  H4   108.35  3.000
 ZOA  H5   C01  H3   107.14  3.000
 ZOA  H4   C01  H3   109.37  3.000
 ZOA  H5   C01  C02  109.87  3.000
 ZOA  H4   C01  C02  112.07  3.000
 ZOA  H3   C01  C02  109.89  3.000

loop_
_chem_comp_tor.comp_id
_chem_comp_tor.id
_chem_comp_tor.atom_id_1
_chem_comp_tor.atom_id_2
_chem_comp_tor.atom_id_3
_chem_comp_tor.atom_id_4
_chem_comp_tor.value_angle
_chem_comp_tor.value_angle_esd
_chem_comp_tor.period
 ZOA  CONST_01  C20  C19  C18  C17     0.00   0.0  0
 ZOA  CONST_02  C20  C25  C26  C17     0.00   0.0  0
 ZOA  CONST_03  C19  C18  C17  C26     0.00   0.0  0
 ZOA  CONST_04  C19  C20  C25  C26     0.00   0.0  0
 ZOA  CONST_05  C02  N30  N29  C28   180.00   0.0  0
 ZOA  CONST_06  C11  N30  N29  C28     0.00   0.0  0
 ZOA  CONST_07  N30  C11  C12  C28     0.00   0.0  0
 ZOA  CONST_08  N10  C11  C12  C28   180.00   0.0  0
 ZOA  CONST_09  C12  C11  N30  C02   180.00   0.0  0
 ZOA  CONST_10  N10  C11  N30  C02     0.00   0.0  0
 ZOA  CONST_11  N10  C09  C03  C02     0.00   0.0  0
 ZOA  CONST_12  N29  N30  C02  C03   180.00   0.0  0
 ZOA  CONST_13  C11  N30  C02  C03     0.00   0.0  0
 ZOA  CONST_14  C11  N10  C09  C03     0.00   0.0  0
 ZOA  CONST_15  N30  C02  C03  C09     0.00   0.0  0
 ZOA  CONST_16  N30  C11  N10  C09     0.00   0.0  0
 ZOA  CONST_17  C12  C11  N10  C09   180.00   0.0  0
 ZOA  CONST_18  N29  N30  C11  N10   180.00   0.0  0
 ZOA  CONST_19  N29  C28  C12  C11     0.00   0.0  0
 ZOA  CONST_20  N30  N29  C28  C12     0.00   0.0  0
 ZOA  CONST_21  N29  N30  C11  C12     0.00   0.0  0
 ZOA  CONST_22  C25  C26  C17  C18     0.00   0.0  0
 ZOA  CONST_23  C25  C20  C19  C18     0.00   0.0  0
 ZOA  CONST_24  S21  C20  C25  C26   180.00   0.0  0
 ZOA  CONST_25  N29  N30  C02  C01     0.00   0.0  0
 ZOA  CONST_26  C11  N30  C02  C01   180.00   0.0  0
 ZOA  CONST_27  C09  C03  C02  C01   180.00   0.0  0
 ZOA  CONST_28  N30  C02  C03  C04   180.00   0.0  0
 ZOA  CONST_29  N10  C09  C03  C04   180.00   0.0  0
 ZOA  CONST_30  N13  C12  C11  N10     0.00   0.0  0
 ZOA  CONST_31  N29  C28  C12  N13   180.00   0.0  0
 ZOA  CONST_32  N30  C11  C12  N13   180.00   0.0  0
 ZOA  CONST_33  C19  C18  C17  C16   180.00   0.0  0
 ZOA  CONST_34  C25  C26  C17  C16   180.00   0.0  0
 ZOA  CONST_35  S21  C20  C19  C18   180.00   0.0  0
 ZOA  CONST_36  H17  C19  C18  C17   180.00   0.0  0
 ZOA  CONST_37  H20  C25  C26  C17   180.00   0.0  0
 ZOA  CONST_38  H16  C18  C19  C20   180.00   0.0  0
 ZOA  CONST_39  H1   C26  C25  C20   180.00   0.0  0
 ZOA  CONST_40  H16  C18  C17  C26   180.00   0.0  0
 ZOA  CONST_41  H11  C09  C03  C02   180.00   0.0  0
 ZOA  CONST_42  H2   C28  C12  C11   180.00   0.0  0
 ZOA  CONST_43  H11  C09  N10  C11   180.00   0.0  0
 ZOA  CONST_44  H1   C26  C17  C18   180.00   0.0  0
 ZOA  CONST_45  H20  C25  C20  C19   180.00   0.0  0
 ZOA  CONST_46  H17  C19  C20  C25   180.00   0.0  0
 ZOA  CONST_47  H2   C28  N29  N30   180.00   0.0  0
 ZOA  CONST_52  N15  C14  N13  C12   180.00   0.0  0
 ZOA  CONST_53  S27  C14  N13  C12     0.00   0.0  0
 ZOA  CONST_54  C16  N15  C14  N13   180.00   0.0  0
 ZOA  CONST_55  S27  C14  N15  C16     0.00   0.0  0
 ZOA  CONST_56  H13  N15  C14  N13     0.00   0.0  0
 ZOA  CONST_57  H12  N13  C14  N15     0.00   0.0  0
 ZOA  CONST_58  H12  N13  C14  S27   180.00   0.0  0
 ZOA  CONST_59  H13  N15  C14  S27   180.00   0.0  0
 ZOA  Var_01    N15  C16  C17  C26   -77.01  30.0  2
 ZOA  Var_02    C04  C03  C02  C01    -4.96  30.0  1
 ZOA  Var_03    O08  C04  C03  C02   -25.62  30.0  2
 ZOA  Var_04    O05  C04  C03  C02   155.53  30.0  2
 ZOA  Var_05    C09  C03  C04  O05   -26.88  30.0  2
 ZOA  Var_06    C09  C03  C04  O08   151.97  30.0  2
 ZOA  Var_07    C18  C17  C16  N15   101.66  30.0  2
 ZOA  Var_08    N23  S21  C20  C19   -80.81  30.0  2
 ZOA  Var_09    O22  S21  C20  C19   160.76  30.0  2
 ZOA  Var_10    O24  S21  C20  C19    30.56  30.0  2
 ZOA  Var_11    C25  C20  S21  O22   -18.70  30.0  3
 ZOA  Var_12    C25  C20  S21  N23    99.72  30.0  3
 ZOA  Var_13    C25  C20  S21  O24  -148.91  30.0  3
 ZOA  Var_14    H14  C16  C17  C26   162.95  30.0  2
 ZOA  Var_15    H15  C16  C17  C26    43.76  30.0  2
 ZOA  Var_16    H3   C01  C02  C03  -137.01  30.0  2
 ZOA  Var_17    H4   C01  C02  C03   -15.18  30.0  2
 ZOA  Var_18    H5   C01  C02  C03   105.34  30.0  2
 ZOA  Var_19    H11  C09  C03  C04     2.92  30.0  1
 ZOA  Var_20    H14  C16  C17  C18   -18.38  30.0  2
 ZOA  Var_21    H15  C16  C17  C18  -137.57  30.0  2
 ZOA  Var_22    H3   C01  C02  N30    41.57  30.0  2
 ZOA  Var_23    H4   C01  C02  N30   163.40  30.0  2
 ZOA  Var_24    H5   C01  C02  N30   -76.08  30.0  2
 ZOA  Var_25    C14  N15  C16  C17    99.60  30.0  1
 ZOA  Var_26    C06  O05  C04  C03   175.85  30.0  3
 ZOA  Var_27    H13  N15  C16  C17   -74.20  30.0  1
 ZOA  Var_28    H18  N23  S21  C20   160.42  30.0  3
 ZOA  Var_29    H19  N23  S21  C20   -74.77  30.0  3
 ZOA  Var_30    C07  C06  O05  C04  -176.98  30.0  1
 ZOA  Var_31    O08  C04  O05  C06    -3.00  30.0  1
 ZOA  Var_32    H6   C06  O05  C04   -56.07  30.0  1
 ZOA  Var_33    H7   C06  O05  C04    62.17  30.0  1
 ZOA  Var_34    H8   C07  C06  O05  -179.73  30.0  3
 ZOA  Var_35    H9   C07  C06  O05   -60.70  30.0  3
 ZOA  Var_36    H10  C07  C06  O05    61.23  30.0  3
 ZOA  Var_37    H14  C16  N15  C14  -139.13  30.0  3
 ZOA  Var_38    H15  C16  N15  C14   -22.65  30.0  3
 ZOA  Var_39    H18  N23  S21  O22   -84.97  30.0  3
 ZOA  Var_40    H19  N23  S21  O22    39.84  30.0  3
 ZOA  Var_41    H18  N23  S21  O24    46.16  30.0  3
 ZOA  Var_42    H19  N23  S21  O24   170.97  30.0  3

loop_
_chem_comp_plane_atom.comp_id
_chem_comp_plane_atom.plane_id
_chem_comp_plane_atom.atom_id
_chem_comp_plane_atom.dist_esd
 ZOA  plan-1  C17  0.020
 ZOA  plan-1  C20  0.020
 ZOA  plan-1  C26  0.020
 ZOA  plan-1  C16  0.020
 ZOA  plan-1  C18  0.020
 ZOA  plan-1  C19  0.020
 ZOA  plan-1  S21  0.020
 ZOA  plan-1  C25  0.020
 ZOA  plan-1  H1   0.020
 ZOA  plan-1  H16  0.020
 ZOA  plan-1  H17  0.020
 ZOA  plan-1  H20  0.020
 ZOA  plan-2  C28  0.020
 ZOA  plan-2  C02  0.020
 ZOA  plan-2  N10  0.020
 ZOA  plan-2  C11  0.020
 ZOA  plan-2  C12  0.020
 ZOA  plan-2  N13  0.020
 ZOA  plan-2  N29  0.020
 ZOA  plan-2  N30  0.020
 ZOA  plan-2  H2   0.020
 ZOA  plan-3  C12  0.020
 ZOA  plan-3  N13  0.020
 ZOA  plan-3  C14  0.020
 ZOA  plan-3  N15  0.020
 ZOA  plan-3  C16  0.020
 ZOA  plan-3  S27  0.020
 ZOA  plan-3  H12  0.020
 ZOA  plan-3  H13  0.020
 ZOA  plan-4  C03  0.020
 ZOA  plan-4  C04  0.020
 ZOA  plan-4  O05  0.020
 ZOA  plan-4  O08  0.020

