# electronic Ligand Builder and Optimisation Workbench (eLBOW)
#   - a module of PHENIX version dev-svn-
#   - file written: Sat May  9 17:21:39 2020
#   Inital geometry file: a 134 line input string
#   Ligand name: (4-{[4-(4-chlorophenyl)pyrimidin-2-yl]amino}phenyl)[4-(2-hydroxyethyl)piperazin-1-yl]methanone
#   Quantum optimisation: True
#   Method: PBEh-3c
#   Random seed: 3628800
#   SMILES string: OCCN1CCN(CC1)C(=O)c2ccc(Nc3nccc(n3)c4ccc(Cl)cc4)cc2
#
data_comp_list
loop_
_chem_comp.id
_chem_comp.three_letter_code
_chem_comp.name
_chem_comp.group
_chem_comp.number_atoms_all
_chem_comp.number_atoms_nh
_chem_comp.desc_level
_chem_comp.initial_date
_chem_comp.modified_date
_chem_comp.source
 XNM  XNM  (4-{[4-(4-chlorophenyl)pyrimidin-2-yl]amino}phenyl)[4-(2-hydroxyethyl)piperazin-1-yl]methanone  ligand  55  31  .  2021-08-24  2023-02-15
;
Directly from eLBOW using geometry from QM method PBEh-3c with CPCM solvent model
Validated by Mogul as PERFECT
;

data_comp_XNM
loop_
_chem_comp_atom.comp_id
_chem_comp_atom.atom_id
_chem_comp_atom.type_symbol
_chem_comp_atom.type_energy
_chem_comp_atom.charge
_chem_comp_atom.partial_charge
_chem_comp_atom.x
_chem_comp_atom.y
_chem_comp_atom.z
 XNM  CLAA  CL  CL    0  -0.116  -9.7938  -1.7187   1.1485
 XNM  CAB   C   CR6   0  -0.049  -8.2894  -1.0177   0.6625
 XNM  CAC   C   CR16  0  -0.187  -8.2376  -0.2401  -0.4837
 XNM  CAD   C   CR16  0  -0.329  -7.0306   0.3232  -0.8631
 XNM  CAE   C   CR16  0  -0.193  -7.1531  -1.2417   1.4255
 XNM  CAF   C   CR16  0  -0.278  -5.9532  -0.6765   1.0309
 XNM  CAG   C   CR6   0   0.064  -5.8723   0.1174  -0.1141
 XNM  CAH   C   CR6   0   0.309  -4.5796   0.7147  -0.5083
 XNM  NAI   N   N     0  -0.498  -3.5033   0.2814   0.1302
 XNM  CAJ   C   CR6   0   0.609  -2.3229   0.8070  -0.1981
 XNM  NAK   N   NH1   0  -0.772  -1.2764   0.3021   0.5153
 XNM  CAL   C   CR6   0   0.369   0.0788   0.5903   0.5008
 XNM  CAM   C   CR16  0  -0.306   0.7028   1.4966  -0.3619
 XNM  CAN   C   CR16  0  -0.263   2.0688   1.7094  -0.2675
 XNM  OAO   O   O     0  -0.492   4.6435   2.5288   0.8210
 XNM  CAP   C   CR16  0  -0.402  -4.4717   1.6971  -1.4953
 XNM  CAQ   C   CR16  0   0.010  -3.2012   2.1673  -1.7565
 XNM  NAR   N   N     0  -0.465  -2.1179   1.7360  -1.1241
 XNM  CAS   C   CR16  0  -0.347   0.8668  -0.0919   1.4378
 XNM  CAT   C   CR16  0  -0.249   2.2302   0.1114   1.5006
 XNM  CAU   C   CR6   0  -0.089   2.8561   1.0146   0.6431
 XNM  CAV   C   C     0   0.515   4.3044   1.3522   0.7647
 XNM  NAW   N   NT    0  -0.456   5.1847   0.3308   0.8585
 XNM  CAX   C   CH2   0  -0.317   6.5858   0.5850   1.1405
 XNM  CAY   C   CH2   0  -0.287   7.4559   0.2634  -0.0619
 XNM  CAZ   C   CH2   0  -0.324   4.9519  -1.0213   0.3799
 XNM  CBA   C   CH2   0  -0.271   5.8481  -1.3166  -0.8132
 XNM  NBB   N   NT    0  -0.418   7.2430  -1.1059  -0.4867
 XNM  CBC   C   CH2   0  -0.293   8.1139  -1.5071  -1.5739
 XNM  CBD   C   CH2   0  -0.173   9.5639  -1.6838  -1.1721
 XNM  OBE   O   OH1   0  -0.669   9.6571  -2.6821  -0.1819
 XNM  HAC   H   HCR6  0   0.286  -9.1251  -0.0751  -1.0788
 XNM  HAD   H   HCR6  0   0.268  -7.0126   0.9199  -1.7650
 XNM  HAE   H   HCR6  0   0.285  -7.2006  -1.8498   2.3185
 XNM  HAF   H   HCR6  0   0.270  -5.0671  -0.8514   1.6250
 XNM  HNAK  H   HNH1  0   0.411  -1.5621  -0.3897   1.1921
 XNM  HAM   H   HCR6  0   0.288   0.1259   2.0359  -1.0942
 XNM  HAN   H   HCR6  0   0.259   2.5268   2.4294  -0.9341
 XNM  HAP   H   HCR6  0   0.277  -5.3200   2.0923  -2.0315
 XNM  HAQ   H   HCR6  0   0.279  -3.0458   2.9307  -2.5103
 XNM  HAS   H   HCR6  0   0.273   0.4002  -0.7869   2.1264
 XNM  HAT   H   HCR6  0   0.270   2.8049  -0.4272   2.2441
 XNM  HAX   H   HCH2  0   0.264   6.7203   1.6220   1.4347
 XNM  HAXA  H   HCH2  0   0.246   6.8866  -0.0460   1.9825
 XNM  HAY   H   HCH2  0   0.200   7.2434   0.9831  -0.8721
 XNM  HAYA  H   HCH2  0   0.246   8.4982   0.4079   0.2269
 XNM  HAZ   H   HCH2  0   0.244   5.1582  -1.7320   1.1852
 XNM  HAZA  H   HCH2  0   0.273   3.9156  -1.1525   0.0816
 XNM  HBA   H   HCH2  0   0.247   5.7013  -2.3596  -1.1034
 XNM  HBAA  H   HCH2  0   0.195   5.5194  -0.6951  -1.6653
 XNM  HBC   H   HCH2  0   0.235   7.7474  -2.4606  -1.9649
 XNM  HBCA  H   HCH2  0   0.199   8.0825  -0.7959  -2.4169
 XNM  HBD   H   HCH2  0   0.204  10.1208  -1.9542  -2.0789
 XNM  HBDA  H   HCH2  0   0.198   9.9883  -0.7330  -0.8261
 XNM  HOBE  H   HOH1  0   0.452  10.5832  -2.7766   0.0567

loop_
_chem_comp_bond.comp_id
_chem_comp_bond.atom_id_1
_chem_comp_bond.atom_id_2
_chem_comp_bond.type
_chem_comp_bond.value_dist
_chem_comp_bond.value_dist_esd
_chem_comp_bond.value_dist_neutron
 XNM  CAB  CLAA  single    1.729  0.020  1.729
 XNM  CAE  CAB   aromatic  1.387  0.020  1.387
 XNM  CAB  CAC   aromatic  1.386  0.020  1.386
 XNM  CAD  CAC   aromatic  1.385  0.020  1.385
 XNM  CAC  HAC   single    0.930  0.020  1.080
 XNM  CAG  CAD   aromatic  1.395  0.020  1.395
 XNM  CAD  HAD   single    0.930  0.020  1.080
 XNM  CAF  CAE   aromatic  1.384  0.020  1.384
 XNM  CAE  HAE   single    0.930  0.020  1.080
 XNM  CAF  CAG   aromatic  1.396  0.020  1.396
 XNM  CAF  HAF   single    0.930  0.020  1.080
 XNM  CAH  CAG   single    1.478  0.020  1.478
 XNM  CAP  CAH   aromatic  1.397  0.020  1.397
 XNM  CAH  NAI   aromatic  1.324  0.020  1.324
 XNM  CAJ  NAI   aromatic  1.333  0.020  1.333
 XNM  NAR  CAJ   aromatic  1.328  0.020  1.328
 XNM  CAJ  NAK   single    1.363  0.020  1.363
 XNM  NAK  CAL   single    1.386  0.020  1.386
 XNM  NAK  HNAK  single    0.860  0.020  1.020
 XNM  CAL  CAM   aromatic  1.398  0.020  1.398
 XNM  CAL  CAS   aromatic  1.402  0.020  1.402
 XNM  CAM  CAN   aromatic  1.386  0.020  1.386
 XNM  CAM  HAM   single    0.930  0.020  1.080
 XNM  CAN  CAU   aromatic  1.390  0.020  1.390
 XNM  CAN  HAN   single    0.930  0.020  1.080
 XNM  OAO  CAV   double    1.226  0.020  1.226
 XNM  CAQ  CAP   aromatic  1.380  0.020  1.380
 XNM  CAP  HAP   single    0.930  0.020  1.080
 XNM  CAQ  NAR   aromatic  1.327  0.020  1.327
 XNM  CAQ  HAQ   single    0.930  0.020  1.080
 XNM  CAS  CAT   aromatic  1.380  0.020  1.380
 XNM  CAS  HAS   single    0.930  0.020  1.080
 XNM  CAT  CAU   aromatic  1.394  0.020  1.394
 XNM  CAT  HAT   single    0.930  0.020  1.080
 XNM  CAU  CAV   single    1.492  0.020  1.492
 XNM  CAV  NAW   single    1.352  0.020  1.352
 XNM  NAW  CAX   single    1.452  0.020  1.452
 XNM  NAW  CAZ   single    1.453  0.020  1.453
 XNM  CAX  CAY   single    1.519  0.020  1.519
 XNM  CAX  HAX   single    0.970  0.020  1.090
 XNM  CAX  HAXA  single    0.970  0.020  1.090
 XNM  CAY  NBB   single    1.449  0.020  1.449
 XNM  CAY  HAY   single    0.970  0.020  1.090
 XNM  CAY  HAYA  single    0.970  0.020  1.090
 XNM  CAZ  CBA   single    1.521  0.020  1.521
 XNM  CAZ  HAZ   single    0.970  0.020  1.090
 XNM  CAZ  HAZA  single    0.970  0.020  1.090
 XNM  CBA  NBB   single    1.448  0.020  1.448
 XNM  CBA  HBA   single    0.970  0.020  1.090
 XNM  CBA  HBAA  single    0.970  0.020  1.090
 XNM  NBB  CBC   single    1.450  0.020  1.450
 XNM  CBC  CBD   single    1.515  0.020  1.515
 XNM  CBC  HBC   single    0.970  0.020  1.090
 XNM  CBC  HBCA  single    0.970  0.020  1.090
 XNM  CBD  OBE   single    1.409  0.020  1.409
 XNM  CBD  HBD   single    0.970  0.020  1.090
 XNM  CBD  HBDA  single    0.970  0.020  1.090
 XNM  OBE  HOBE  single    0.850  0.020  0.980

loop_
_chem_comp_angle.comp_id
_chem_comp_angle.atom_id_1
_chem_comp_angle.atom_id_2
_chem_comp_angle.atom_id_3
_chem_comp_angle.value_angle
_chem_comp_angle.value_angle_esd
 XNM  CAE   CAB  CAC   120.99  3.000
 XNM  CAC   CAB  CLAA  119.49  3.000
 XNM  CAE   CAB  CLAA  119.51  3.000
 XNM  HAC   CAC  CAD   120.16  3.000
 XNM  HAC   CAC  CAB   120.67  3.000
 XNM  CAD   CAC  CAB   119.16  3.000
 XNM  HAD   CAD  CAG   121.03  3.000
 XNM  HAD   CAD  CAC   117.86  3.000
 XNM  CAG   CAD  CAC   121.11  3.000
 XNM  HAE   CAE  CAF   120.21  3.000
 XNM  HAE   CAE  CAB   120.61  3.000
 XNM  CAF   CAE  CAB   119.18  3.000
 XNM  HAF   CAF  CAG   119.69  3.000
 XNM  HAF   CAF  CAE   119.20  3.000
 XNM  CAG   CAF  CAE   121.10  3.000
 XNM  CAH   CAG  CAF   119.97  3.000
 XNM  CAH   CAG  CAD   121.58  3.000
 XNM  CAF   CAG  CAD   118.45  3.000
 XNM  CAP   CAH  NAI   120.54  3.000
 XNM  NAI   CAH  CAG   116.75  3.000
 XNM  CAP   CAH  CAG   122.71  3.000
 XNM  CAJ   NAI  CAH   118.16  3.000
 XNM  NAR   CAJ  NAK   120.37  3.000
 XNM  NAK   CAJ  NAI   113.88  3.000
 XNM  NAR   CAJ  NAI   125.75  3.000
 XNM  HNAK  NAK  CAL   115.24  3.000
 XNM  HNAK  NAK  CAJ   112.80  3.000
 XNM  CAL   NAK  CAJ   131.93  3.000
 XNM  CAS   CAL  CAM   118.50  3.000
 XNM  CAS   CAL  NAK   116.21  3.000
 XNM  CAM   CAL  NAK   125.29  3.000
 XNM  HAM   CAM  CAN   119.83  3.000
 XNM  HAM   CAM  CAL   120.34  3.000
 XNM  CAN   CAM  CAL   119.83  3.000
 XNM  HAN   CAN  CAU   119.74  3.000
 XNM  HAN   CAN  CAM   118.50  3.000
 XNM  CAU   CAN  CAM   121.75  3.000
 XNM  HAP   CAP  CAQ   120.35  3.000
 XNM  HAP   CAP  CAH   123.25  3.000
 XNM  CAQ   CAP  CAH   116.40  3.000
 XNM  HAQ   CAQ  NAR   116.32  3.000
 XNM  HAQ   CAQ  CAP   120.25  3.000
 XNM  NAR   CAQ  CAP   123.43  3.000
 XNM  CAQ   NAR  CAJ   115.72  3.000
 XNM  HAS   CAS  CAT   119.40  3.000
 XNM  HAS   CAS  CAL   119.66  3.000
 XNM  CAT   CAS  CAL   120.95  3.000
 XNM  HAT   CAT  CAU   120.42  3.000
 XNM  HAT   CAT  CAS   118.83  3.000
 XNM  CAU   CAT  CAS   120.74  3.000
 XNM  CAV   CAU  CAT   122.16  3.000
 XNM  CAV   CAU  CAN   119.35  3.000
 XNM  CAT   CAU  CAN   118.21  3.000
 XNM  NAW   CAV  CAU   117.83  3.000
 XNM  NAW   CAV  OAO   122.82  3.000
 XNM  CAU   CAV  OAO   119.30  3.000
 XNM  CAZ   NAW  CAX   112.43  3.000
 XNM  CAZ   NAW  CAV   125.16  3.000
 XNM  CAX   NAW  CAV   120.65  3.000
 XNM  HAXA  CAX  HAX   107.94  3.000
 XNM  HAXA  CAX  CAY   109.24  3.000
 XNM  HAX   CAX  CAY   110.22  3.000
 XNM  HAXA  CAX  NAW   108.29  3.000
 XNM  HAX   CAX  NAW   109.84  3.000
 XNM  CAY   CAX  NAW   111.23  3.000
 XNM  HAYA  CAY  HAY   106.96  3.000
 XNM  HAYA  CAY  NBB   110.06  3.000
 XNM  HAY   CAY  NBB   111.86  3.000
 XNM  HAYA  CAY  CAX   108.04  3.000
 XNM  HAY   CAY  CAX   109.42  3.000
 XNM  NBB   CAY  CAX   110.37  3.000
 XNM  HAZA  CAZ  HAZ   107.67  3.000
 XNM  HAZA  CAZ  CBA   108.86  3.000
 XNM  HAZ   CAZ  CBA   109.89  3.000
 XNM  HAZA  CAZ  NAW   110.84  3.000
 XNM  HAZ   CAZ  NAW   109.38  3.000
 XNM  CBA   CAZ  NAW   110.16  3.000
 XNM  HBAA  CBA  HBA   106.99  3.000
 XNM  HBAA  CBA  NBB   112.25  3.000
 XNM  HBA   CBA  NBB   109.17  3.000
 XNM  HBAA  CBA  CAZ   108.69  3.000
 XNM  HBA   CBA  CAZ   108.33  3.000
 XNM  NBB   CBA  CAZ   111.26  3.000
 XNM  CBC   NBB  CBA   111.68  3.000
 XNM  CBC   NBB  CAY   113.15  3.000
 XNM  CBA   NBB  CAY   110.18  3.000
 XNM  HBCA  CBC  HBC   106.22  3.000
 XNM  HBCA  CBC  CBD   107.76  3.000
 XNM  HBC   CBC  CBD   108.29  3.000
 XNM  HBCA  CBC  NBB   112.18  3.000
 XNM  HBC   CBC  NBB   107.94  3.000
 XNM  CBD   CBC  NBB   114.10  3.000
 XNM  HBDA  CBD  HBD   106.12  3.000
 XNM  HBDA  CBD  OBE   111.51  3.000
 XNM  HBD   CBD  OBE   111.86  3.000
 XNM  HBDA  CBD  CBC   110.66  3.000
 XNM  HBD   CBD  CBC   107.17  3.000
 XNM  OBE   CBD  CBC   109.41  3.000
 XNM  HOBE  OBE  CBD   107.93  3.000

loop_
_chem_comp_tor.comp_id
_chem_comp_tor.id
_chem_comp_tor.atom_id_1
_chem_comp_tor.atom_id_2
_chem_comp_tor.atom_id_3
_chem_comp_tor.atom_id_4
_chem_comp_tor.value_angle
_chem_comp_tor.value_angle_esd
_chem_comp_tor.period
 XNM  CONST_01  CAG  CAF  CAE  CAB      0.00   0.0  0
 XNM  CONST_02  CAG  CAD  CAC  CAB      0.00   0.0  0
 XNM  CONST_03  CAF  CAE  CAB  CAC      0.00   0.0  0
 XNM  CONST_04  CAF  CAG  CAD  CAC      0.00   0.0  0
 XNM  CONST_05  CAH  CAG  CAD  CAC    180.00   0.0  0
 XNM  CONST_06  CAE  CAB  CAC  CAD      0.00   0.0  0
 XNM  CONST_07  CAE  CAF  CAG  CAD      0.00   0.0  0
 XNM  CONST_08  CAP  CAH  CAG  CAD      0.00   0.0  0
 XNM  CONST_09  NAI  CAH  CAG  CAD    180.00   0.0  0
 XNM  CONST_10  CAH  CAG  CAF  CAE    180.00   0.0  0
 XNM  CONST_11  CAP  CAH  CAG  CAF    180.00   0.0  0
 XNM  CONST_12  NAI  CAH  CAG  CAF      0.00   0.0  0
 XNM  CONST_13  CAQ  CAP  CAH  CAG    180.00   0.0  0
 XNM  CONST_14  CAJ  NAI  CAH  CAG    180.00   0.0  0
 XNM  CONST_15  NAR  CAQ  CAP  CAH      0.00   0.0  0
 XNM  CONST_16  NAR  CAJ  NAI  CAH      0.00   0.0  0
 XNM  CONST_17  CAQ  CAP  CAH  NAI      0.00   0.0  0
 XNM  CONST_18  CAQ  NAR  CAJ  NAI      0.00   0.0  0
 XNM  CONST_19  CAP  CAH  NAI  CAJ      0.00   0.0  0
 XNM  CONST_20  CAP  CAQ  NAR  CAJ      0.00   0.0  0
 XNM  CONST_21  CAU  CAN  CAM  CAL      0.00   0.0  0
 XNM  CONST_22  CAU  CAT  CAS  CAL      0.00   0.0  0
 XNM  CONST_23  CAT  CAS  CAL  CAM      0.00   0.0  0
 XNM  CONST_24  CAT  CAU  CAN  CAM      0.00   0.0  0
 XNM  CONST_25  CAS  CAL  CAM  CAN      0.00   0.0  0
 XNM  CONST_26  CAS  CAT  CAU  CAN      0.00   0.0  0
 XNM  CONST_27  CAF  CAE  CAB  CLAA   180.00   0.0  0
 XNM  CONST_28  CAD  CAC  CAB  CLAA   180.00   0.0  0
 XNM  CONST_29  NAK  CAJ  NAI  CAH    180.00   0.0  0
 XNM  CONST_30  CAQ  NAR  CAJ  NAK    180.00   0.0  0
 XNM  CONST_31  CAN  CAM  CAL  NAK    180.00   0.0  0
 XNM  CONST_32  CAT  CAS  CAL  NAK    180.00   0.0  0
 XNM  CONST_33  CAV  CAU  CAN  CAM    180.00   0.0  0
 XNM  CONST_34  CAV  CAU  CAT  CAS    180.00   0.0  0
 XNM  CONST_35  CAX  NAW  CAV  CAU    180.00   0.0  0
 XNM  CONST_37  HAF  CAF  CAE  CAB    180.00   0.0  0
 XNM  CONST_38  HAD  CAD  CAC  CAB    180.00   0.0  0
 XNM  CONST_39  HAE  CAE  CAB  CAC    180.00   0.0  0
 XNM  CONST_40  HAC  CAC  CAB  CAE    180.00   0.0  0
 XNM  CONST_41  HAP  CAP  CAH  CAG      0.00   0.0  0
 XNM  CONST_42  HAQ  CAQ  CAP  CAH    180.00   0.0  0
 XNM  CONST_43  HAN  CAN  CAM  CAL    180.00   0.0  0
 XNM  CONST_44  HAT  CAT  CAS  CAL    180.00   0.0  0
 XNM  CONST_45  HAS  CAS  CAL  CAM    180.00   0.0  0
 XNM  CONST_46  HAM  CAM  CAL  CAS    180.00   0.0  0
 XNM  CONST_47  CAX  NAW  CAV  OAO      0.00   0.0  0
 XNM  Var_01    NBB  CAY  CAX  NAW    -55.88  30.0  1
 XNM  Var_02    NBB  CBA  CAZ  NAW     56.02  30.0  1
 XNM  Var_03    CBA  CAZ  NAW  CAX    -53.69  30.0  1
 XNM  Var_04    CBA  NBB  CAY  CAX     58.27  30.0  1
 XNM  Var_05    CAZ  NAW  CAX  CAY     54.18  30.0  1
 XNM  Var_06    CAZ  CBA  NBB  CAY    -58.90  30.0  1
 XNM  Var_07    CAL  NAK  CAJ  NAI   -178.61  30.0  2
 XNM  Var_08    CAM  CAL  NAK  CAJ     -3.02  30.0  2
 XNM  Var_09    NAW  CAV  CAU  CAN   -136.96  30.0  2
 XNM  Var_10    CBD  CBC  NBB  CAY     71.33  30.0  3
 XNM  Var_11    OBE  CBD  CBC  NBB     60.27  30.0  3

loop_
_chem_comp_plane_atom.comp_id
_chem_comp_plane_atom.plane_id
_chem_comp_plane_atom.atom_id
_chem_comp_plane_atom.dist_esd
 XNM  plan-1  CLAA  0.020
 XNM  plan-1  CAB   0.020
 XNM  plan-1  CAC   0.020
 XNM  plan-1  CAD   0.020
 XNM  plan-1  CAE   0.020
 XNM  plan-1  CAF   0.020
 XNM  plan-1  CAG   0.020
 XNM  plan-1  CAH   0.020
 XNM  plan-1  HAC   0.020
 XNM  plan-1  HAD   0.020
 XNM  plan-1  HAE   0.020
 XNM  plan-1  HAF   0.020
 XNM  plan-2  NAK   0.020
 XNM  plan-2  CAL   0.020
 XNM  plan-2  CAM   0.020
 XNM  plan-2  CAN   0.020
 XNM  plan-2  CAS   0.020
 XNM  plan-2  CAT   0.020
 XNM  plan-2  CAU   0.020
 XNM  plan-2  CAV   0.020
 XNM  plan-2  HAM   0.020
 XNM  plan-2  HAN   0.020
 XNM  plan-2  HAS   0.020
 XNM  plan-2  HAT   0.020
 XNM  plan-3  CAG   0.020
 XNM  plan-3  CAH   0.020
 XNM  plan-3  NAI   0.020
 XNM  plan-3  CAJ   0.020
 XNM  plan-3  NAK   0.020
 XNM  plan-3  CAP   0.020
 XNM  plan-3  CAQ   0.020
 XNM  plan-3  NAR   0.020
 XNM  plan-3  HAP   0.020
 XNM  plan-3  HAQ   0.020
 XNM  plan-4  OAO   0.020
 XNM  plan-4  CAU   0.020
 XNM  plan-4  CAV   0.020
 XNM  plan-4  NAW   0.020
 XNM  plan-4  CAX   0.020
 XNM  plan-4  CAZ   0.020

