# electronic Ligand Builder and Optimisation Workbench (eLBOW)
#   - a module of PHENIX version dev-svn-
#   - file written: Tue Aug  3 00:43:08 2021
#   Inital geometry file: a 163 line input string
#   Ligand name: (2S,4S)-2-[(R)-carboxy{[(2R)-2-{[(4-ethyl-2,3-dioxopiperazin-1-yl)carbonyl]amino}-2-phenylacetyl]amino}methyl]-5,5-dimethyl-1,3-thiazolidine-4-carboxylic acid
#   Quantum optimisation: True
#   Method: PBEh-3c
#   Random seed: 3628800
#   SMILES string: CCN1CCN(C(=O)N[C@@H](C(=O)N[C@@H]([C@H]2N[C@@H](C(O)=O)C(C)(C)S2)C(O)=O)c3ccccc3)C(=O)C1=O
#
data_comp_list
loop_
_chem_comp.id
_chem_comp.three_letter_code
_chem_comp.name
_chem_comp.group
_chem_comp.number_atoms_all
_chem_comp.number_atoms_nh
_chem_comp.desc_level
_chem_comp.initial_date
_chem_comp.modified_date
_chem_comp.source
 VPP  VPP  '(2S,4S)-2-[(R)-carboxy{[(2R)-2-{[(4-ethyl-2,3-dioxopiperazin-1-yl)carbonyl]amino}-2-phenylacetyl]amino}methyl]-5,5-dimethyl-1,3-thiazolidine-4-carboxylic acid'  ligand  66  37  .  2022-11-18  2022-11-18
;
Directly from eLBOW using geometry from QM method PBEh-3c with CPCM solvent model
Validated by Mogul as PERFECT
;

data_comp_VPP
loop_
_chem_comp_atom.comp_id
_chem_comp_atom.atom_id
_chem_comp_atom.type_symbol
_chem_comp_atom.type_energy
_chem_comp_atom.charge
_chem_comp_atom.partial_charge
_chem_comp_atom.x
_chem_comp_atom.y
_chem_comp_atom.z
 VPP  S    S  S2    0   0.026   -7.8061   5.6150  24.0118
 VPP  O01  O  OH1   0  -0.572   -4.9090   4.6839  25.3620
 VPP  O02  O  O     0  -0.426   -6.6275   5.3793  19.4635
 VPP  O03  O  OH1   0  -0.579   -8.7825   5.9565  19.3613
 VPP  O06  O  O     0  -0.469   -2.6162   7.1124  24.9441
 VPP  O04  O  O     0  -0.488    0.0808   9.6378  21.8489
 VPP  O05  O  O     0  -0.437    1.0861   7.6696  25.2808
 VPP  O    O  O     0  -0.462    3.5721   8.0064  26.1669
 VPP  N02  N  NR15  0  -0.571   -6.3869   6.5053  21.9416
 VPP  N03  N  NH1   0  -0.643   -4.2225   7.4818  23.4175
 VPP  N04  N  NH1   0  -0.698   -0.7481   8.3979  23.5337
 VPP  N01  N  NT    0  -0.590    1.5703   8.7644  23.3334
 VPP  N    N  NT    0  -0.453    4.2892   8.4240  24.0556
 VPP  C17  C  CR15  0  -0.254   -6.5168   6.7705  23.3427
 VPP  C19  C  CR5   0  -0.239   -8.3966   5.1489  22.3286
 VPP  C18  C  CR15  0  -0.157   -7.7072   6.2304  21.4332
 VPP  C20  C  CH1   0  -0.172   -5.1926   6.6619  24.0984
 VPP  C01  C  C     0   0.546   -4.7141   5.2149  24.1721
 VPP  C02  C  CH3   0  -0.639   -7.9272   3.7333  22.0108
 VPP  C03  C  CH3   0  -0.628   -9.9153   5.2420  22.2848
 VPP  C04  C  C     0   0.538   -7.6244   5.8117  19.9817
 VPP  C21  C  C     0   0.573   -2.9922   7.6518  23.9173
 VPP  CA   C  CH1   0  -0.265   -2.1092   8.6164  23.1284
 VPP  C05  C  CR6   0   0.154   -2.5932  10.0299  23.3882
 VPP  C07  C  CR16  0  -0.313   -3.3198  10.7099  22.4196
 VPP  C08  C  CR16  0  -0.289   -2.3503  10.6402  24.6148
 VPP  C09  C  CH2   0  -0.303    2.6480   9.3586  22.5393
 VPP  C10  C  CH2   0  -0.315    3.8965   8.5288  22.6637
 VPP  C11  C  C     0   0.482    1.8828   8.1874  24.5276
 VPP  C12  C  CR16  0  -0.242   -3.8028  11.9874  22.6715
 VPP  C13  C  CR16  0  -0.240   -2.8285  11.9179  24.8661
 VPP  C14  C  C     0   0.484    3.3587   8.2062  24.9871
 VPP  C15  C  CH2   0  -0.320    5.7046   8.3361  24.3809
 VPP  C16  C  CR16  0  -0.263   -3.5575  12.5945  23.8954
 VPP  C    C  CH3   0  -0.664    6.2803   6.9520  24.1250
 VPP  O07  O  O     0  -0.434   -4.2282   4.6337  23.2343
 VPP  H1   H  HOH1  0   0.487   -4.6385   3.7526  25.3651
 VPP  H2   H  HOH1  0   0.489   -8.7157   5.6450  18.4454
 VPP  H3   H  HNR5  0   0.366   -5.7724   5.7156  21.7691
 VPP  H5   H  HNH1  0   0.417   -4.4617   7.8597  22.5124
 VPP  H6   H  HNH1  0   0.427   -0.5564   7.8730  24.3784
 VPP  H7   H  HCR5  0   0.318   -6.8930   7.7858  23.4838
 VPP  H8   H  HCR5  0   0.304   -8.3042   7.1461  21.5009
 VPP  H9   H  HCH1  0   0.317   -5.3544   7.0374  25.1114
 VPP  H10  H  HCH3  0   0.255   -8.3138   3.0363  22.7541
 VPP  H11  H  HCH3  0   0.239   -8.2962   3.4019  21.0372
 VPP  H12  H  HCH3  0   0.235   -6.8407   3.6456  22.0176
 VPP  H13  H  HCH3  0   0.246  -10.3644   4.5693  23.0157
 VPP  H14  H  HCH3  0   0.242  -10.2572   6.2544  22.4994
 VPP  H15  H  HCH3  0   0.244  -10.2920   4.9521  21.3032
 VPP  H16  H  HCH1  0   0.311   -2.2203   8.3971  22.0623
 VPP  H17  H  HCR6  0   0.257   -3.5034  10.2464  21.4570
 VPP  H18  H  HCR6  0   0.254   -1.7824  10.1213  25.3780
 VPP  H19  H  HCH2  0   0.274    2.8322  10.3844  22.8651
 VPP  H20  H  HCH2  0   0.290    2.3431   9.3837  21.4984
 VPP  H21  H  HCH2  0   0.269    3.7507   7.5418  22.2153
 VPP  H22  H  HCH2  0   0.282    4.6938   9.0268  22.1149
 VPP  H23  H  HCR6  0   0.260   -4.3641  12.5098  21.9078
 VPP  H24  H  HCR6  0   0.260   -2.6337  12.3852  25.8227
 VPP  H25  H  HCH2  0   0.257    6.2225   9.0814  23.7759
 VPP  H26  H  HCH2  0   0.264    5.8382   8.6194  25.4228
 VPP  H27  H  HCR6  0   0.259   -3.9294  13.5913  24.0929
 VPP  H28  H  HCH3  0   0.242    7.3427   6.9430  24.3676
 VPP  H29  H  HCH3  0   0.235    5.7867   6.1998  24.7400
 VPP  H30  H  HCH3  0   0.235    6.1773   6.6603  23.0792
 VPP  C06  C  C     0   0.784    0.2496   8.9699  22.8505

loop_
_chem_comp_bond.comp_id
_chem_comp_bond.atom_id_1
_chem_comp_bond.atom_id_2
_chem_comp_bond.type
_chem_comp_bond.value_dist
_chem_comp_bond.value_dist_esd
_chem_comp_bond.value_dist_neutron
 VPP  O02  C04  double    1.204  0.020  1.204
 VPP  O03  C04  single    1.322  0.020  1.322
 VPP  C04  C18  single    1.513  0.020  1.513
 VPP  O07  C01  double    1.206  0.020  1.206
 VPP  N02  C18  single    1.441  0.020  1.441
 VPP  N02  C17  single    1.432  0.020  1.432
 VPP  C18  C19  single    1.564  0.020  1.564
 VPP  C07  C12  aromatic  1.389  0.020  1.389
 VPP  C07  C05  aromatic  1.389  0.020  1.389
 VPP  O04  C06  double    1.216  0.020  1.216
 VPP  C12  C16  aromatic  1.388  0.020  1.388
 VPP  C01  C20  single    1.526  0.020  1.526
 VPP  C01  O01  single    1.317  0.020  1.317
 VPP  C02  C19  single    1.525  0.020  1.525
 VPP  N03  C20  single    1.441  0.020  1.441
 VPP  N03  C21  single    1.339  0.020  1.339
 VPP  CA   C05  single    1.516  0.020  1.516
 VPP  CA   C21  single    1.527  0.020  1.527
 VPP  CA   N04  single    1.437  0.020  1.437
 VPP  C06  N04  single    1.338  0.020  1.338
 VPP  C06  N01  single    1.421  0.020  1.421
 VPP  C09  C10  single    1.504  0.020  1.504
 VPP  C09  N01  single    1.465  0.020  1.465
 VPP  C19  C03  single    1.522  0.020  1.522
 VPP  C19  S    single    1.844  0.020  1.844
 VPP  C17  C20  single    1.529  0.020  1.529
 VPP  C17  S    single    1.856  0.020  1.856
 VPP  C05  C08  aromatic  1.391  0.020  1.391
 VPP  C16  C13  aromatic  1.390  0.020  1.390
 VPP  C10  N    single    1.450  0.020  1.450
 VPP  C21  O06  double    1.219  0.020  1.219
 VPP  N01  C11  single    1.363  0.020  1.363
 VPP  C08  C13  aromatic  1.387  0.020  1.387
 VPP  N    C15  single    1.455  0.020  1.455
 VPP  N    C14  single    1.334  0.020  1.334
 VPP  C    C15  single    1.521  0.020  1.521
 VPP  C11  O05  double    1.212  0.020  1.212
 VPP  C11  C14  single    1.546  0.020  1.546
 VPP  C14  O    double    1.216  0.020  1.216
 VPP  O01  H1   single    0.850  0.020  0.980
 VPP  O03  H2   single    0.850  0.020  0.980
 VPP  N02  H3   single    0.890  0.020  1.040
 VPP  N03  H5   single    0.860  0.020  1.020
 VPP  N04  H6   single    0.860  0.020  1.020
 VPP  C17  H7   single    0.970  0.020  1.090
 VPP  C18  H8   single    0.970  0.020  1.090
 VPP  C20  H9   single    0.970  0.020  1.090
 VPP  C02  H10  single    0.970  0.020  1.090
 VPP  C02  H11  single    0.970  0.020  1.090
 VPP  C02  H12  single    0.970  0.020  1.090
 VPP  C03  H13  single    0.970  0.020  1.090
 VPP  C03  H14  single    0.970  0.020  1.090
 VPP  C03  H15  single    0.970  0.020  1.090
 VPP  CA   H16  single    0.970  0.020  1.090
 VPP  C07  H17  single    0.930  0.020  1.080
 VPP  C08  H18  single    0.930  0.020  1.080
 VPP  C09  H19  single    0.970  0.020  1.090
 VPP  C09  H20  single    0.970  0.020  1.090
 VPP  C10  H21  single    0.970  0.020  1.090
 VPP  C10  H22  single    0.970  0.020  1.090
 VPP  C12  H23  single    0.930  0.020  1.080
 VPP  C13  H24  single    0.930  0.020  1.080
 VPP  C15  H25  single    0.970  0.020  1.090
 VPP  C15  H26  single    0.970  0.020  1.090
 VPP  C16  H27  single    0.930  0.020  1.080
 VPP  C    H28  single    0.970  0.020  1.090
 VPP  C    H29  single    0.970  0.020  1.090
 VPP  C    H30  single    0.970  0.020  1.090

loop_
_chem_comp_angle.comp_id
_chem_comp_angle.atom_id_1
_chem_comp_angle.atom_id_2
_chem_comp_angle.atom_id_3
_chem_comp_angle.value_angle
_chem_comp_angle.value_angle_esd
 VPP  C19  S    C17   92.91  3.000
 VPP  H1   O01  C01  110.40  3.000
 VPP  H2   O03  C04  110.36  3.000
 VPP  H3   N02  C18  110.25  3.000
 VPP  H3   N02  C17  111.42  3.000
 VPP  C18  N02  C17  107.30  3.000
 VPP  H5   N03  C21  120.33  3.000
 VPP  H5   N03  C20  118.49  3.000
 VPP  C21  N03  C20  120.96  3.000
 VPP  H6   N04  C06  120.43  3.000
 VPP  H6   N04  CA   119.56  3.000
 VPP  C06  N04  CA   119.83  3.000
 VPP  C11  N01  C09  118.57  3.000
 VPP  C11  N01  C06  124.90  3.000
 VPP  C09  N01  C06  116.16  3.000
 VPP  C15  N    C14  120.82  3.000
 VPP  C14  N    C10  119.54  3.000
 VPP  C15  N    C10  118.84  3.000
 VPP  H7   C17  C20  107.50  3.000
 VPP  H7   C17  N02  109.27  3.000
 VPP  C20  C17  N02  113.08  3.000
 VPP  H7   C17  S    107.03  3.000
 VPP  C20  C17  S    112.29  3.000
 VPP  N02  C17  S    107.49  3.000
 VPP  C03  C19  C02  110.97  3.000
 VPP  C03  C19  C18  112.40  3.000
 VPP  C02  C19  C18  112.76  3.000
 VPP  C03  C19  S    109.29  3.000
 VPP  C02  C19  S    109.05  3.000
 VPP  C18  C19  S    101.93  3.000
 VPP  H8   C18  C04  108.69  3.000
 VPP  H8   C18  C19  107.60  3.000
 VPP  C04  C18  C19  112.45  3.000
 VPP  H8   C18  N02  108.55  3.000
 VPP  C19  C18  N02  109.49  3.000
 VPP  C04  C18  N02  109.94  3.000
 VPP  H9   C20  C01  109.12  3.000
 VPP  H9   C20  C17  107.80  3.000
 VPP  C01  C20  C17  111.28  3.000
 VPP  H9   C20  N03  110.01  3.000
 VPP  C17  C20  N03  108.01  3.000
 VPP  C01  C20  N03  110.56  3.000
 VPP  O07  C01  C20  123.10  3.000
 VPP  C20  C01  O01  112.30  3.000
 VPP  O07  C01  O01  124.60  3.000
 VPP  H12  C02  H11  108.52  3.000
 VPP  H12  C02  H10  107.33  3.000
 VPP  H11  C02  H10  107.09  3.000
 VPP  H12  C02  C19  112.35  3.000
 VPP  H11  C02  C19  111.31  3.000
 VPP  H10  C02  C19  110.03  3.000
 VPP  H15  C03  H14  108.40  3.000
 VPP  H15  C03  H13  107.29  3.000
 VPP  H14  C03  H13  108.18  3.000
 VPP  H15  C03  C19  110.75  3.000
 VPP  H14  C03  C19  111.35  3.000
 VPP  H13  C03  C19  110.73  3.000
 VPP  C18  C04  O03  111.84  3.000
 VPP  C18  C04  O02  123.89  3.000
 VPP  O03  C04  O02  124.25  3.000
 VPP  CA   C21  N03  114.75  3.000
 VPP  CA   C21  O06  122.42  3.000
 VPP  N03  C21  O06  122.80  3.000
 VPP  H16  CA   C05  108.75  3.000
 VPP  H16  CA   C21  108.55  3.000
 VPP  C05  CA   C21  108.40  3.000
 VPP  H16  CA   N04  109.91  3.000
 VPP  C21  CA   N04  107.81  3.000
 VPP  C05  CA   N04  113.31  3.000
 VPP  C08  C05  C07  119.43  3.000
 VPP  C08  C05  CA   120.28  3.000
 VPP  C07  C05  CA   120.26  3.000
 VPP  H17  C07  C12  119.71  3.000
 VPP  H17  C07  C05  119.90  3.000
 VPP  C12  C07  C05  120.39  3.000
 VPP  H18  C08  C13  119.61  3.000
 VPP  H18  C08  C05  120.15  3.000
 VPP  C13  C08  C05  120.23  3.000
 VPP  H20  C09  H19  108.18  3.000
 VPP  H20  C09  C10  108.99  3.000
 VPP  H19  C09  C10  110.70  3.000
 VPP  H20  C09  N01  108.83  3.000
 VPP  H19  C09  N01  110.09  3.000
 VPP  C10  C09  N01  110.00  3.000
 VPP  H22  C10  H21  107.69  3.000
 VPP  H22  C10  C09  108.29  3.000
 VPP  H21  C10  C09  110.68  3.000
 VPP  H22  C10  N    108.59  3.000
 VPP  H21  C10  N    111.37  3.000
 VPP  C09  C10  N    110.12  3.000
 VPP  C14  C11  N01  118.31  3.000
 VPP  C14  C11  O05  116.61  3.000
 VPP  N01  C11  O05  125.07  3.000
 VPP  H23  C12  C16  120.19  3.000
 VPP  H23  C12  C07  119.76  3.000
 VPP  C16  C12  C07  120.05  3.000
 VPP  H24  C13  C16  120.10  3.000
 VPP  H24  C13  C08  119.72  3.000
 VPP  C16  C13  C08  120.18  3.000
 VPP  C11  C14  N    117.40  3.000
 VPP  C11  C14  O    117.01  3.000
 VPP  N    C14  O    125.58  3.000
 VPP  H26  C15  H25  107.15  3.000
 VPP  H26  C15  C    110.59  3.000
 VPP  H25  C15  C    110.41  3.000
 VPP  H26  C15  N    108.54  3.000
 VPP  H25  C15  N    107.25  3.000
 VPP  C    C15  N    112.68  3.000
 VPP  H27  C16  C13  120.08  3.000
 VPP  H27  C16  C12  120.20  3.000
 VPP  C13  C16  C12  119.71  3.000
 VPP  H30  C    H29  108.29  3.000
 VPP  H30  C    H28  107.66  3.000
 VPP  H29  C    H28  108.07  3.000
 VPP  H30  C    C15  111.66  3.000
 VPP  H29  C    C15  111.21  3.000
 VPP  H28  C    C15  109.82  3.000
 VPP  N01  C06  N04  117.24  3.000
 VPP  N01  C06  O04  119.24  3.000
 VPP  N04  C06  O04  123.52  3.000

loop_
_chem_comp_tor.comp_id
_chem_comp_tor.id
_chem_comp_tor.atom_id_1
_chem_comp_tor.atom_id_2
_chem_comp_tor.atom_id_3
_chem_comp_tor.atom_id_4
_chem_comp_tor.value_angle
_chem_comp_tor.value_angle_esd
_chem_comp_tor.period
 VPP  CONST_01  C16  C12  C07  C05    0.00   0.0  0
 VPP  CONST_02  C16  C13  C08  C05    0.00   0.0  0
 VPP  CONST_03  C13  C16  C12  C07    0.00   0.0  0
 VPP  CONST_04  C13  C08  C05  C07    0.00   0.0  0
 VPP  CONST_05  C12  C07  C05  C08    0.00   0.0  0
 VPP  CONST_06  C12  C16  C13  C08    0.00   0.0  0
 VPP  CONST_07  C14  C11  N01  C09    0.00   0.0  0
 VPP  CONST_08  C11  C14  N    C10    0.00   0.0  0
 VPP  CONST_09  C12  C07  C05  CA   180.00   0.0  0
 VPP  CONST_10  C13  C08  C05  CA   180.00   0.0  0
 VPP  CONST_11  C09  N01  C11  O05  180.00   0.0  0
 VPP  CONST_12  C10  N    C14  O    180.00   0.0  0
 VPP  CONST_13  C14  C11  N01  C06  180.00   0.0  0
 VPP  CONST_14  C15  N    C14  C11  180.00   0.0  0
 VPP  CONST_15  H23  C12  C07  C05  180.00   0.0  0
 VPP  CONST_16  H24  C13  C08  C05  180.00   0.0  0
 VPP  CONST_17  H27  C16  C12  C07  180.00   0.0  0
 VPP  CONST_18  H18  C08  C05  C07  180.00   0.0  0
 VPP  CONST_19  H17  C07  C05  C08  180.00   0.0  0
 VPP  CONST_20  C09  N01  C06  O04    0.00   0.0  0
 VPP  CONST_21  C11  N01  C06  O04  180.00   0.0  0
 VPP  CONST_22  C06  N01  C11  O05    0.00   0.0  0
 VPP  CONST_23  C15  N    C14  O      0.00   0.0  0
 VPP  CONST_24  C09  N01  C06  N04  180.00   0.0  0
 VPP  CONST_25  C11  N01  C06  N04    0.00   0.0  0
 VPP  CONST_26  CA   N04  C06  N01  180.00   0.0  0
 VPP  CONST_27  H6   N04  C06  N01    0.00   0.0  0
 VPP  CONST_28  H2   O03  C04  C18  180.00   0.0  0
 VPP  CONST_29  C20  N03  C21  O06    0.00   0.0  0
 VPP  CONST_30  CA   N04  C06  O04    0.00   0.0  0
 VPP  CONST_31  CA   C21  N03  C20  180.00   0.0  0
 VPP  CONST_32  H5   N03  C21  O06  180.00   0.0  0
 VPP  CONST_33  H1   O01  C01  C20  180.00   0.0  0
 VPP  Var_01    N    C10  C09  N01  -57.95  30.0  1
 VPP  Var_02    N    C14  C11  N01  -18.96  30.0  1
 VPP  Var_03    C18  C19  S    C17  -12.65  30.0  1
 VPP  Var_04    C14  N    C10  C09   42.68  30.0  1
 VPP  Var_05    C11  N01  C09  C10   36.89  30.0  1
 VPP  Var_06    C    C15  N    C10  -77.18  30.0  3
 VPP  Var_07    H10  C02  C19  S     58.87  30.0  3
 VPP  Var_08    H13  C03  C19  S    -60.02  30.0  3
 VPP  Var_09    H28  C    C15  N    179.06  30.0  3

loop_
_chem_comp_chir.comp_id
_chem_comp_chir.id
_chem_comp_chir.atom_id_centre
_chem_comp_chir.atom_id_1
_chem_comp_chir.atom_id_2
_chem_comp_chir.atom_id_3
_chem_comp_chir.volume_sign
 VPP  chir_01  C17  N02  C20  S    positiv
 VPP  chir_02  C18  N02  C19  C04  positiv
 VPP  chir_03  C20  N03  C17  C01  negativ
 VPP  chir_04  CA   N04  C05  C21  positiv

loop_
_chem_comp_plane_atom.comp_id
_chem_comp_plane_atom.plane_id
_chem_comp_plane_atom.atom_id
_chem_comp_plane_atom.dist_esd
 VPP  plan-1  O01  0.020
 VPP  plan-1  C20  0.020
 VPP  plan-1  C01  0.020
 VPP  plan-1  O07  0.020
 VPP  plan-1  H1   0.020
 VPP  plan-2  O02  0.020
 VPP  plan-2  O03  0.020
 VPP  plan-2  C18  0.020
 VPP  plan-2  C04  0.020
 VPP  plan-2  H2   0.020
 VPP  plan-3  CA   0.020
 VPP  plan-3  C05  0.020
 VPP  plan-3  C07  0.020
 VPP  plan-3  C08  0.020
 VPP  plan-3  C12  0.020
 VPP  plan-3  C13  0.020
 VPP  plan-3  C16  0.020
 VPP  plan-3  H17  0.020
 VPP  plan-3  H18  0.020
 VPP  plan-3  H23  0.020
 VPP  plan-3  H24  0.020
 VPP  plan-3  H27  0.020
 VPP  plan-4  O04  0.020
 VPP  plan-4  O05  0.020
 VPP  plan-4  N04  0.020
 VPP  plan-4  N01  0.020
 VPP  plan-4  CA   0.020
 VPP  plan-4  C09  0.020
 VPP  plan-4  C11  0.020
 VPP  plan-4  C14  0.020
 VPP  plan-4  H6   0.020
 VPP  plan-4  C06  0.020
 VPP  plan-5  O06  0.020
 VPP  plan-5  N03  0.020
 VPP  plan-5  C20  0.020
 VPP  plan-5  C21  0.020
 VPP  plan-5  CA   0.020
 VPP  plan-5  H5   0.020
 VPP  plan-6  O    0.020
 VPP  plan-6  N    0.020
 VPP  plan-6  C10  0.020
 VPP  plan-6  C11  0.020
 VPP  plan-6  C14  0.020
 VPP  plan-6  C15  0.020

