# electronic Ligand Builder and Optimisation Workbench (eLBOW)
#   - a module of PHENIX version dev-svn-
#   - file written: Fri May  1 03:06:19 2020
#   Inital geometry file: a 146 line input string
#   Ligand name: (3R)-3-[(7-{[(2S)-2-amino-2-(2-methoxyphenyl)ethyl]amino}-5-methyl[1,2,4]triazolo[1,5-a]pyrimidin-2-yl)amino]-3-(3-chlorophenyl)propanenitrile
#   Quantum optimisation: True
#   Method: PBEh-3c
#   Random seed: 3628800
#   SMILES string: COc1ccccc1[C@H](N)CNc2cc(C)nc3nc(N[C@H](CC#N)c4cccc(Cl)c4)nn23
#
data_comp_list
loop_
_chem_comp.id
_chem_comp.three_letter_code
_chem_comp.name
_chem_comp.group
_chem_comp.number_atoms_all
_chem_comp.number_atoms_nh
_chem_comp.desc_level
_chem_comp.initial_date
_chem_comp.modified_date
_chem_comp.source
 F6D  F6D  (3R)-3-[(7-{[(2S)-2-amino-2-(2-methoxyphenyl)ethyl]amino}-5-methyl[1,2,4]triazolo[1,5-a]pyrimidin-2-yl)amino]-3-(3-chlorophenyl)propanenitrile  ligand  59  34  .  2021-08-09  2021-08-09  
;
Directly from eLBOW using geometry from QM method PBEh-3c with CPCM solvent model
Validated by Mogul as PERFECT
;

data_comp_F6D
loop_
_chem_comp_atom.comp_id
_chem_comp_atom.atom_id
_chem_comp_atom.type_symbol
_chem_comp_atom.type_energy
_chem_comp_atom.charge
_chem_comp_atom.partial_charge
_chem_comp_atom.x
_chem_comp_atom.y
_chem_comp_atom.z
 F6D  C1   C   CR6   0   0.361   6.4030  -1.2724   0.8023
 F6D  C2   C   CR16  0  -0.379   7.7856  -1.4117   0.7205
 F6D  C3   C   CR16  0  -0.254   8.4054  -1.4615  -0.5227
 F6D  C11  C   CR6   0   0.255   0.7364   2.2523  -2.5000
 F6D  C12  C   CH3   0  -0.723   1.0034   2.8294  -3.8543
 F6D  C13  C   CR56  0   0.602  -0.7521   1.7797  -0.8810
 F6D  C14  C   CR5   0   0.596  -1.5316   1.0997   0.9426
 F6D  C15  C   CH1   0  -0.168  -3.8364   0.9100   1.6813
 F6D  C16  C   CH2   0  -0.549  -4.5874   0.9456   3.0186
 F6D  C17  C   CSP   0   0.128  -4.1868   2.0857   3.8294
 F6D  C18  C   CR6   0   0.149  -4.3580  -0.2370   0.8386
 F6D  C19  C   CR16  0  -0.299  -3.8851  -1.5330   1.0089
 F6D  C20  C   CR16  0  -0.244  -4.4012  -2.5708   0.2468
 F6D  C21  C   CR16  0  -0.226  -5.3950  -2.3328  -0.6920
 F6D  C22  C   CR6   0  -0.022  -5.8604  -1.0372  -0.8506
 F6D  C23  C   CR16  0  -0.265  -5.3526   0.0104  -0.0992
 F6D  CL   CL  CL    0  -0.127  -7.0968  -0.7138  -2.0225
 F6D  N5   N   NS    0  -0.266  -3.8761   2.9907   4.4676
 F6D  N4   N   NH1   0  -0.690  -2.4207   0.8641   1.9423
 F6D  N3   N   N     0  -0.552  -1.8933   1.6877  -0.2122
 F6D  N6   N   N     0  -0.381  -0.2500   0.7958   1.0709
 F6D  N7   N   N     0  -0.433   0.2443   1.2419  -0.1063
 F6D  N2   N   N     0  -0.499  -0.5270   2.2866  -2.0821
 F6D  C10  C   CR16  0  -0.486   1.7885   1.7202  -1.7564
 F6D  C9   C   CR6   0   0.711   1.5387   1.1863  -0.4911
 F6D  C8   C   CH2   0  -0.310   3.8145   0.4469   0.1236
 F6D  C7   C   CH1   0  -0.170   4.1246  -1.0118  -0.2707
 F6D  N    N   NH2   0  -0.785   3.4543  -1.4399  -1.4826
 F6D  C6   C   CR6   0   0.039   5.6259  -1.1878  -0.3653
 F6D  O    O   O2    0  -0.473   5.7289  -1.2169   1.9692
 F6D  C    C   CH3   0  -0.436   6.4461  -1.3430   3.1804
 F6D  C5   C   CR16  0  -0.311   6.2737  -1.2488  -1.5906
 F6D  C4   C   CR16  0  -0.268   7.6551  -1.3807  -1.6822
 F6D  H1   H   HCR6  0   0.279   8.3939  -1.4852   1.6117
 F6D  H2   H   HCR6  0   0.257   9.4815  -1.5662  -0.5723
 F6D  H3   H   HCH3  0   0.258   0.6974   3.8756  -3.8873
 F6D  H4   H   HCH3  0   0.248   2.0564   2.7722  -4.1212
 F6D  H5   H   HCH3  0   0.258   0.4256   2.3009  -4.6134
 F6D  H6   H   HCH1  0   0.296  -4.0495   1.8424   1.1557
 F6D  H7   H   HCH2  0   0.336  -5.6614   1.0098   2.8396
 F6D  H8   H   HCH2  0   0.321  -4.4138   0.0329   3.5940
 F6D  H9   H   HCR6  0   0.253  -3.1061  -1.7408   1.7317
 F6D  H10  H   HCR6  0   0.271  -4.0268  -3.5770   0.3801
 F6D  H11  H   HCR6  0   0.282  -5.7934  -3.1404  -1.2906
 F6D  H12  H   HCR6  0   0.277  -5.7252   1.0168  -0.2461
 F6D  H13  H   HNH1  0   0.396  -2.0968   0.2559   2.6790
 F6D  H14  H   HCR6  0   0.281   2.7906   1.7380  -2.1541
 F6D  H15  H   HNH1  0   0.417   2.0283   0.3167   1.2394
 F6D  H16  H   HCH2  0   0.258   4.1563   1.1201  -0.6637
 F6D  H17  H   HCH2  0   0.279   4.3530   0.7256   1.0288
 F6D  H18  H   HCH1  0   0.257   3.7522  -1.6539   0.5325
 F6D  H19  H   HNH2  0   0.361   2.4601  -1.5201  -1.3172
 F6D  H20  H   HNH2  0   0.345   3.5666  -0.7620  -2.2268
 F6D  H22  H   HCH3  0   0.260   5.7124  -1.2891   3.9806
 F6D  H23  H   HCH3  0   0.229   6.9700  -2.2999   3.2451
 F6D  H24  H   HCH3  0   0.228   7.1702  -0.5352   3.3128
 F6D  H25  H   HCR6  0   0.247   5.6910  -1.2032  -2.5015
 F6D  H26  H   HCR6  0   0.250   8.1328  -1.4256  -2.6519
 F6D  N1   N   NH1   0  -0.667   2.4068   0.6598   0.3681

loop_
_chem_comp_bond.comp_id
_chem_comp_bond.atom_id_1
_chem_comp_bond.atom_id_2
_chem_comp_bond.type
_chem_comp_bond.value_dist
_chem_comp_bond.value_dist_esd
_chem_comp_bond.value_dist_neutron
 F6D  C4   C3   aromatic  1.383  0.020  1.383
 F6D  C4   C5   aromatic  1.391  0.020  1.391
 F6D  C3   C2   aromatic  1.390  0.020  1.390
 F6D  C5   C6   aromatic  1.387  0.020  1.387
 F6D  C2   C1   aromatic  1.392  0.020  1.392
 F6D  C6   C1   aromatic  1.405  0.020  1.405
 F6D  C6   C7   single    1.515  0.020  1.515
 F6D  C8   C7   single    1.543  0.020  1.543
 F6D  C8   N1   single    1.445  0.020  1.445
 F6D  C1   O    single    1.349  0.020  1.349
 F6D  C7   N    single    1.450  0.020  1.450
 F6D  N1   C9   single    1.330  0.020  1.330
 F6D  O    C    single    1.413  0.020  1.413
 F6D  C9   C10  aromatic  1.396  0.020  1.396
 F6D  C9   N7   aromatic  1.352  0.020  1.352
 F6D  N5   C17  triple    1.150  0.020  1.150
 F6D  C10  C11  aromatic  1.394  0.020  1.394
 F6D  N6   N7   aromatic  1.352  0.020  1.352
 F6D  N6   C14  aromatic  1.323  0.020  1.323
 F6D  C17  C16  single    1.455  0.020  1.455
 F6D  N7   C13  aromatic  1.372  0.020  1.372
 F6D  C19  C20  aromatic  1.387  0.020  1.387
 F6D  C19  C18  aromatic  1.390  0.020  1.390
 F6D  C15  C16  single    1.534  0.020  1.534
 F6D  C15  C18  single    1.516  0.020  1.516
 F6D  C15  N4   single    1.440  0.020  1.440
 F6D  C20  C21  aromatic  1.388  0.020  1.388
 F6D  C14  N4   single    1.359  0.020  1.359
 F6D  C14  N3   aromatic  1.345  0.020  1.345
 F6D  C11  C12  single    1.496  0.020  1.496
 F6D  C11  N2   aromatic  1.331  0.020  1.331
 F6D  C18  C23  aromatic  1.389  0.020  1.389
 F6D  C13  N2   aromatic  1.323  0.020  1.323
 F6D  C13  N3   aromatic  1.326  0.020  1.326
 F6D  C21  C22  aromatic  1.386  0.020  1.386
 F6D  C23  C22  aromatic  1.386  0.020  1.386
 F6D  C22  CL   single    1.734  0.020  1.734
 F6D  C2   H1   single    0.930  0.020  1.080
 F6D  C3   H2   single    0.930  0.020  1.080
 F6D  C12  H3   single    0.970  0.020  1.090
 F6D  C12  H4   single    0.970  0.020  1.090
 F6D  C12  H5   single    0.970  0.020  1.090
 F6D  C15  H6   single    0.970  0.020  1.090
 F6D  C16  H7   single    0.970  0.020  1.090
 F6D  C16  H8   single    0.970  0.020  1.090
 F6D  C19  H9   single    0.930  0.020  1.080
 F6D  C20  H10  single    0.930  0.020  1.080
 F6D  C21  H11  single    0.930  0.020  1.080
 F6D  C23  H12  single    0.930  0.020  1.080
 F6D  N4   H13  single    0.890  0.020  1.040
 F6D  C10  H14  single    0.930  0.020  1.080
 F6D  N1   H15  single    0.860  0.020  1.020
 F6D  C8   H16  single    0.970  0.020  1.090
 F6D  C8   H17  single    0.970  0.020  1.090
 F6D  C7   H18  single    0.970  0.020  1.090
 F6D  N    H19  single    0.890  0.020  1.040
 F6D  N    H20  single    0.890  0.020  1.040
 F6D  C    H22  single    0.970  0.020  1.090
 F6D  C    H23  single    0.970  0.020  1.090
 F6D  C    H24  single    0.970  0.020  1.090
 F6D  C5   H25  single    0.930  0.020  1.080
 F6D  C4   H26  single    0.930  0.020  1.080

loop_
_chem_comp_angle.comp_id
_chem_comp_angle.atom_id_1
_chem_comp_angle.atom_id_2
_chem_comp_angle.atom_id_3
_chem_comp_angle.value_angle
_chem_comp_angle.value_angle_esd
 F6D  O    C1   C6   116.11  3.000
 F6D  O    C1   C2   123.46  3.000
 F6D  C6   C1   C2   120.43  3.000
 F6D  H1   C2   C3   118.93  3.000
 F6D  H1   C2   C1   121.13  3.000
 F6D  C3   C2   C1   119.93  3.000
 F6D  H2   C3   C4   120.43  3.000
 F6D  H2   C3   C2   119.20  3.000
 F6D  C4   C3   C2   120.38  3.000
 F6D  C10  C11  N2   123.97  3.000
 F6D  N2   C11  C12  116.33  3.000
 F6D  C10  C11  C12  119.70  3.000
 F6D  H5   C12  H4   108.46  3.000
 F6D  H5   C12  H3   107.17  3.000
 F6D  H4   C12  H3   108.34  3.000
 F6D  H5   C12  C11  110.40  3.000
 F6D  H4   C12  C11  112.00  3.000
 F6D  H3   C12  C11  110.32  3.000
 F6D  N2   C13  N7   122.64  3.000
 F6D  N2   C13  N3   129.12  3.000
 F6D  N7   C13  N3   108.25  3.000
 F6D  N6   C14  N3   116.35  3.000
 F6D  N3   C14  N4   122.11  3.000
 F6D  N6   C14  N4   121.51  3.000
 F6D  H6   C15  N4   107.84  3.000
 F6D  H6   C15  C18  108.15  3.000
 F6D  N4   C15  C18  114.51  3.000
 F6D  H6   C15  C16  107.72  3.000
 F6D  N4   C15  C16  108.90  3.000
 F6D  C18  C15  C16  109.50  3.000
 F6D  H8   C16  H7   106.98  3.000
 F6D  H8   C16  C17  108.50  3.000
 F6D  H7   C16  C17  108.44  3.000
 F6D  H8   C16  C15  111.21  3.000
 F6D  H7   C16  C15  109.90  3.000
 F6D  C17  C16  C15  111.66  3.000
 F6D  N5   C17  C16  180.00  3.000
 F6D  C23  C18  C19  119.49  3.000
 F6D  C23  C18  C15  119.14  3.000
 F6D  C19  C18  C15  121.35  3.000
 F6D  H9   C19  C20  119.39  3.000
 F6D  H9   C19  C18  120.37  3.000
 F6D  C20  C19  C18  120.24  3.000
 F6D  H10  C20  C21  119.39  3.000
 F6D  H10  C20  C19  119.96  3.000
 F6D  C21  C20  C19  120.65  3.000
 F6D  H11  C21  C22  120.75  3.000
 F6D  H11  C21  C20  120.68  3.000
 F6D  C22  C21  C20  118.57  3.000
 F6D  CL   C22  C23  119.13  3.000
 F6D  CL   C22  C21  119.42  3.000
 F6D  C23  C22  C21  121.45  3.000
 F6D  H12  C23  C22  120.19  3.000
 F6D  H12  C23  C18  120.22  3.000
 F6D  C22  C23  C18  119.59  3.000
 F6D  H13  N4   C15  117.86  3.000
 F6D  H13  N4   C14  115.58  3.000
 F6D  C15  N4   C14  120.29  3.000
 F6D  C14  N3   C13  103.41  3.000
 F6D  N7   N6   C14  101.18  3.000
 F6D  C9   N7   N6   125.75  3.000
 F6D  N6   N7   C13  110.81  3.000
 F6D  C9   N7   C13  123.43  3.000
 F6D  C13  N2   C11  115.88  3.000
 F6D  H14  C10  C9   120.46  3.000
 F6D  H14  C10  C11  119.89  3.000
 F6D  C9   C10  C11  119.64  3.000
 F6D  N1   C9   C10  128.33  3.000
 F6D  C10  C9   N7   114.44  3.000
 F6D  N1   C9   N7   117.22  3.000
 F6D  H17  C8   H16  106.68  3.000
 F6D  H17  C8   C7   110.79  3.000
 F6D  H16  C8   C7   109.64  3.000
 F6D  H17  C8   N1   107.66  3.000
 F6D  H16  C8   N1   109.67  3.000
 F6D  C7   C8   N1   112.24  3.000
 F6D  H18  C7   C6   108.37  3.000
 F6D  H18  C7   N    106.44  3.000
 F6D  C6   C7   N    111.83  3.000
 F6D  H18  C7   C8   107.40  3.000
 F6D  N    C7   C8   113.58  3.000
 F6D  C6   C7   C8   108.98  3.000
 F6D  H20  N    H19  106.40  3.000
 F6D  H20  N    C7   111.42  3.000
 F6D  H19  N    C7   109.96  3.000
 F6D  C5   C6   C7   121.54  3.000
 F6D  C7   C6   C1   120.22  3.000
 F6D  C5   C6   C1   118.23  3.000
 F6D  C    O    C1   118.96  3.000
 F6D  H24  C    H23  108.81  3.000
 F6D  H24  C    H22  108.74  3.000
 F6D  H23  C    H22  108.87  3.000
 F6D  H24  C    O    111.97  3.000
 F6D  H23  C    O    111.85  3.000
 F6D  H22  C    O    106.50  3.000
 F6D  H25  C5   C4   118.91  3.000
 F6D  H25  C5   C6   119.34  3.000
 F6D  C4   C5   C6   121.75  3.000
 F6D  H26  C4   C5   120.10  3.000
 F6D  H26  C4   C3   120.62  3.000
 F6D  C5   C4   C3   119.28  3.000
 F6D  H15  N1   C8   117.46  3.000
 F6D  H15  N1   C9   116.56  3.000
 F6D  C8   N1   C9   125.80  3.000

loop_
_chem_comp_tor.comp_id
_chem_comp_tor.id
_chem_comp_tor.atom_id_1
_chem_comp_tor.atom_id_2
_chem_comp_tor.atom_id_3
_chem_comp_tor.atom_id_4
_chem_comp_tor.value_angle
_chem_comp_tor.value_angle_esd
_chem_comp_tor.period
 F6D  CONST_01  C4   C3   C2   C1      0.00   0.0  0
 F6D  CONST_02  C4   C5   C6   C1      0.00   0.0  0
 F6D  CONST_03  C5   C4   C3   C2      0.00   0.0  0
 F6D  CONST_04  C5   C6   C1   C2      0.00   0.0  0
 F6D  CONST_05  C6   C5   C4   C3      0.00   0.0  0
 F6D  CONST_06  C6   C1   C2   C3      0.00   0.0  0
 F6D  CONST_07  N7   C9   C10  C11     0.00   0.0  0
 F6D  CONST_08  N7   C13  N2   C11     0.00   0.0  0
 F6D  CONST_09  N3   C13  N2   C11   180.00   0.0  0
 F6D  CONST_10  C10  C9   N7   C13     0.00   0.0  0
 F6D  CONST_11  C14  N6   N7   C13     0.00   0.0  0
 F6D  CONST_12  C10  C11  N2   C13     0.00   0.0  0
 F6D  CONST_13  N6   C14  N3   C13     0.00   0.0  0
 F6D  CONST_14  C9   N7   N6   C14   180.00   0.0  0
 F6D  CONST_15  N7   C13  N3   C14     0.00   0.0  0
 F6D  CONST_16  N2   C13  N3   C14   180.00   0.0  0
 F6D  CONST_17  C21  C20  C19  C18     0.00   0.0  0
 F6D  CONST_18  C21  C22  C23  C18     0.00   0.0  0
 F6D  CONST_19  C22  C21  C20  C19     0.00   0.0  0
 F6D  CONST_20  C22  C23  C18  C19     0.00   0.0  0
 F6D  CONST_21  C23  C18  C19  C20     0.00   0.0  0
 F6D  CONST_22  C23  C22  C21  C20     0.00   0.0  0
 F6D  CONST_23  N7   N6   C14  N3      0.00   0.0  0
 F6D  CONST_24  C9   N7   C13  N3    180.00   0.0  0
 F6D  CONST_25  N6   N7   C13  N3      0.00   0.0  0
 F6D  CONST_26  C10  C9   N7   N6    180.00   0.0  0
 F6D  CONST_27  N2   C13  N7   N6    180.00   0.0  0
 F6D  CONST_28  C9   C10  C11  N2      0.00   0.0  0
 F6D  CONST_29  C9   N7   C13  N2      0.00   0.0  0
 F6D  CONST_30  C7   C6   C1   C2    180.00   0.0  0
 F6D  CONST_31  O    C1   C2   C3    180.00   0.0  0
 F6D  CONST_32  N1   C9   C10  C11   180.00   0.0  0
 F6D  CONST_33  C9   C10  C11  C12   180.00   0.0  0
 F6D  CONST_34  C13  N2   C11  C12   180.00   0.0  0
 F6D  CONST_35  N1   C9   N7   C13   180.00   0.0  0
 F6D  CONST_36  N4   C14  N3   C13   180.00   0.0  0
 F6D  CONST_37  C20  C19  C18  C15   180.00   0.0  0
 F6D  CONST_38  C22  C23  C18  C15   180.00   0.0  0
 F6D  CONST_39  CL   C22  C23  C18   180.00   0.0  0
 F6D  CONST_40  CL   C22  C21  C20   180.00   0.0  0
 F6D  CONST_41  N7   N6   C14  N4    180.00   0.0  0
 F6D  CONST_42  N1   C9   N7   N6      0.00   0.0  0
 F6D  CONST_43  C4   C5   C6   C7    180.00   0.0  0
 F6D  CONST_44  C5   C6   C1   O     180.00   0.0  0
 F6D  CONST_45  H2   C3   C2   C1    180.00   0.0  0
 F6D  CONST_46  H25  C5   C6   C1    180.00   0.0  0
 F6D  CONST_47  H26  C4   C3   C2    180.00   0.0  0
 F6D  CONST_48  H10  C20  C19  C18   180.00   0.0  0
 F6D  CONST_49  H11  C21  C20  C19   180.00   0.0  0
 F6D  CONST_50  H12  C23  C18  C19   180.00   0.0  0
 F6D  CONST_51  H9   C19  C20  C21   180.00   0.0  0
 F6D  CONST_52  H14  C10  C9   N7    180.00   0.0  0
 F6D  CONST_53  H1   C2   C1   C6    180.00   0.0  0
 F6D  CONST_54  N6   C14  N4   C15   180.00   0.0  0
 F6D  CONST_56  C8   N1   C9   N7    180.00   0.0  0
 F6D  CONST_57  C8   N1   C9   C10     0.00   0.0  0
 F6D  CONST_58  H13  N4   C14  N3    180.00   0.0  0
 F6D  CONST_59  H15  N1   C9   N7      0.00   0.0  0
 F6D  Var_01    H3   C12  C11  N2     58.78  30.0  2
 F6D  Var_02    C7   C8   N1   C9    -99.12  30.0  1
 F6D  Var_03    H22  C    O    C1   -178.95  30.0  3
 F6D  Var_04    H7   C16  C17  N5    -25.46  30.0  3

loop_
_chem_comp_chir.comp_id
_chem_comp_chir.id
_chem_comp_chir.atom_id_centre
_chem_comp_chir.atom_id_1
_chem_comp_chir.atom_id_2
_chem_comp_chir.atom_id_3
_chem_comp_chir.volume_sign
 F6D  chir_01  C15  C16  C18  N4  positiv
 F6D  chir_02  C7   C6   C8   N   negativ

loop_
_chem_comp_plane_atom.comp_id
_chem_comp_plane_atom.plane_id
_chem_comp_plane_atom.atom_id
_chem_comp_plane_atom.dist_esd
 F6D  plan-1  C15  0.020
 F6D  plan-1  C18  0.020
 F6D  plan-1  C19  0.020
 F6D  plan-1  C20  0.020
 F6D  plan-1  C21  0.020
 F6D  plan-1  C22  0.020
 F6D  plan-1  C23  0.020
 F6D  plan-1  CL   0.020
 F6D  plan-1  H9   0.020
 F6D  plan-1  H10  0.020
 F6D  plan-1  H11  0.020
 F6D  plan-1  H12  0.020
 F6D  plan-2  C1   0.020
 F6D  plan-2  C2   0.020
 F6D  plan-2  C3   0.020
 F6D  plan-2  C7   0.020
 F6D  plan-2  C6   0.020
 F6D  plan-2  O    0.020
 F6D  plan-2  C5   0.020
 F6D  plan-2  C4   0.020
 F6D  plan-2  H1   0.020
 F6D  plan-2  H2   0.020
 F6D  plan-2  H25  0.020
 F6D  plan-2  H26  0.020
 F6D  plan-3  C11  0.020
 F6D  plan-3  C12  0.020
 F6D  plan-3  C13  0.020
 F6D  plan-3  C14  0.020
 F6D  plan-3  N4   0.020
 F6D  plan-3  N3   0.020
 F6D  plan-3  N6   0.020
 F6D  plan-3  N7   0.020
 F6D  plan-3  N2   0.020
 F6D  plan-3  C10  0.020
 F6D  plan-3  C9   0.020
 F6D  plan-3  H14  0.020
 F6D  plan-3  N1   0.020
 F6D  plan-4  C14  0.020
 F6D  plan-4  C15  0.020
 F6D  plan-4  N4   0.020
 F6D  plan-4  H13  0.020
 F6D  plan-5  C9   0.020
 F6D  plan-5  C8   0.020
 F6D  plan-5  H15  0.020
 F6D  plan-5  N1   0.020

