# electronic Ligand Builder and Optimisation Workbench (eLBOW)
#   - a module of PHENIX version dev-svn-
#   - file written: Thu Apr  9 23:38:42 2020
#   Inital geometry file: a 164 line input string
#   Ligand name: 2'-{[(5-carbamimidoylpyridin-2-yl)amino]methyl}-4'-ethenyl-4-[(2-methylpropyl)carbamoyl]biphenyl-2-carboxylic acid
#   Quantum optimisation: True
#   Method: PBEh-3c
#   Random seed: 3628800
#   SMILES string: CC(C)CNC(=O)c1ccc(c2ccc(C=C)cc2CNc3ccc(cn3)C(N)=N)c(c1)C(O)=O
#
data_comp_list
loop_
_chem_comp.id
_chem_comp.three_letter_code
_chem_comp.name
_chem_comp.group
_chem_comp.number_atoms_all
_chem_comp.number_atoms_nh
_chem_comp.desc_level
_chem_comp.initial_date
_chem_comp.modified_date
_chem_comp.source
 24X  24X  '2'-{[(5-carbamimidoylpyridin-2-yl)amino]methyl}-4'-ethenyl-4-[(2-methylpropyl)carbamoyl]biphenyl-2-carboxylic acid'  ligand  63  35  .  2021-08-04  2021-08-04  
;
Directly from eLBOW using geometry from QM method PBEh-3c with CPCM solvent model
Validated by Mogul as PERFECT
;

data_comp_24X
loop_
_chem_comp_atom.comp_id
_chem_comp_atom.atom_id
_chem_comp_atom.type_symbol
_chem_comp_atom.type_energy
_chem_comp_atom.charge
_chem_comp_atom.partial_charge
_chem_comp_atom.x
_chem_comp_atom.y
_chem_comp_atom.z
 24X  N1    N  N      0  -0.456   7.6978  -2.1912   3.1774
 24X  C2    C  CR16   0  -0.070   6.6339  -2.9650   3.2705
 24X  C3    C  CR6    0  -0.049   5.4265  -2.5877   3.8499
 24X  C4    C  CR16   0  -0.185   5.3717  -1.2900   4.3625
 24X  C5    C  CR16   0  -0.385   6.4641  -0.4576   4.2718
 24X  C6    C  CR6    0   0.500   7.6316  -0.9376   3.6472
 24X  C7    C  CH2    0  -0.374   8.7715   1.2454   3.6447
 24X  N2    N  NH1    0  -0.677   8.7523  -0.1936   3.5080
 24X  C8    C  CR6    0   0.006   8.3798   0.8112   0.7868
 24X  C17   C  CR16   0  -0.263   7.1274   1.4198   0.7558
 24X  C21   C  CR16   0  -0.299   6.0050   0.7279   0.3347
 24X  C23   C  CR6    0  -0.020   6.1201  -0.5923  -0.0920
 24X  C26   C  CR16   0  -0.295   7.3810  -1.1766  -0.1158
 24X  C29   C  CR6    0  -0.067   8.5087  -0.5067   0.3398
 24X  C9    C  C      0   0.395   9.8242  -1.2630   0.3994
 24X  O2    O  O      0  -0.574  10.5285  -1.0769   1.4162
 24X  O1    O  OC    -1  -0.582  10.0782  -2.0202  -0.5510
 24X  C10   C  C      0   0.539   4.9566  -1.4101  -0.5533
 24X  N3    N  NH1    0  -0.652   3.7410  -0.9899  -0.1634
 24X  O4    O  O      0  -0.497   5.1212  -2.3999  -1.2566
 24X  C11   C  CH2    0  -0.273   2.5194  -1.6889  -0.4944
 24X  C18   C  CH1    0  -0.248   2.1056  -2.7432   0.5333
 24X  C12   C  CH3    0  -0.653   1.8109  -2.1131   1.8886
 24X  C13   C  CH3    0  -0.659   0.8916  -3.5052   0.0135
 24X  C14   C  C      0   0.334   4.2949  -3.5364   3.9067
 24X  N4    N  NH2    0  -0.825   3.3688  -3.2775   4.8817
 24X  N5    N  N      0  -0.655   4.2289  -4.4827   3.0484
 24X  C15   C  CR16   0  -0.319  11.4846   2.9496   0.7973
 24X  C19   C  CR6    0   0.137  11.6698   3.2137   2.1521
 24X  C22   C  CR16   0  -0.389  10.7692   2.6455   3.0588
 24X  C24   C  CR6    0   0.112   9.7114   1.8586   2.6383
 24X  C27   C  CR6    0   0.065   9.5353   1.6083   1.2703
 24X  C30   C  CR16   0  -0.275  10.4297   2.1590   0.3646
 24X  C16   C  C2     0  -0.549  13.0674   4.4758   3.8042
 24X  HN41  H  HNH2   0   0.384   2.6574  -3.9743   5.0353
 24X  HN42  H  HNH2   0   0.387   3.6805  -2.8338   5.7298
 24X  HN5   H  H      0   0.313   3.4259  -5.0798   3.2260
 24X  H2    H  HCR6   0   0.246   6.7369  -3.9690   2.8724
 24X  H5    H  HCR6   0   0.264   6.4153   0.5414   4.6816
 24X  H4    H  HCR6   0   0.256   4.4672  -0.9135   4.8248
 24X  HN2   H  HNH1   0   0.410   9.4555  -0.5923   2.8788
 24X  H71   H  HCH2   0   0.248   9.0681   1.5499   4.6534
 24X  H72   H  HCH2   0   0.246   7.7670   1.6505   3.4844
 24X  H22   H  HCR6   0   0.247  10.8986   2.8123   4.1222
 24X  H20   H  H      0   0.249  13.4514   4.3726   1.7635
 24X  H161  H  H      0   0.249  13.9277   5.1017   3.9971
 24X  H162  H  H      0   0.245  12.4580   4.2190   4.6616
 24X  H15   H  HCR6   0   0.252  12.1707   3.3689   0.0706
 24X  H30   H  HCR6   0   0.247  10.3013   1.9693  -0.6942
 24X  H17   H  HCR6   0   0.250   7.0263   2.4538   1.0625
 24X  H21   H  HCR6   0   0.249   5.0564   1.2501   0.3226
 24X  H26   H  HCR6   0   0.242   7.4854  -2.1951  -0.4644
 24X  HN3   H  HNH1   0   0.399   3.6774  -0.2586   0.5237
 24X  H111  H  HCH2   0   0.244   2.6413  -2.1485  -1.4753
 24X  H112  H  HCH2   0   0.237   1.7254  -0.9425  -0.5900
 24X  H18   H  HCH1   0   0.235   2.9365  -3.4458   0.6589
 24X  H121  H  HCH3   0   0.210   1.0157  -1.3673   1.8065
 24X  H122  H  HCH3   0   0.225   1.4893  -2.8675   2.6068
 24X  H123  H  HCH3   0   0.227   2.6897  -1.6285   2.3150
 24X  H131  H  HCH3   0   0.214   0.0289  -2.8432  -0.0982
 24X  H132  H  HCH3   0   0.229   0.6054  -4.3030   0.7004
 24X  H133  H  HCH3   0   0.226   1.0875  -3.9617  -0.9585
 24X  C20   C  C1     0  -0.230  12.7927   4.0605   2.5684

loop_
_chem_comp_bond.comp_id
_chem_comp_bond.atom_id_1
_chem_comp_bond.atom_id_2
_chem_comp_bond.type
_chem_comp_bond.value_dist
_chem_comp_bond.value_dist_esd
_chem_comp_bond.value_dist_neutron
 24X  N1   C2    aromatic  1.319  0.020  1.319
 24X  N1   C6    aromatic  1.340  0.020  1.340
 24X  C2   C3    aromatic  1.391  0.020  1.391
 24X  C2   H2    single    0.930  0.020  1.080
 24X  C3   C14   single    1.478  0.020  1.478
 24X  C3   C4    aromatic  1.396  0.020  1.396
 24X  C4   C5    aromatic  1.376  0.020  1.376
 24X  C4   H4    single    0.930  0.020  1.080
 24X  C5   C6    aromatic  1.408  0.020  1.408
 24X  C5   H5    single    0.930  0.020  1.080
 24X  C6   N2    single    1.352  0.020  1.352
 24X  C7   N2    single    1.446  0.020  1.446
 24X  C7   H71   single    0.970  0.020  1.090
 24X  C7   H72   single    0.970  0.020  1.090
 24X  C7   C24   single    1.507  0.020  1.507
 24X  N2   HN2   single    0.890  0.020  1.040
 24X  C8   C27   single    1.485  0.020  1.485
 24X  C8   C17   aromatic  1.393  0.020  1.393
 24X  C8   C29   aromatic  1.398  0.020  1.398
 24X  C17  H17   single    0.930  0.020  1.080
 24X  C17  C21   aromatic  1.384  0.020  1.384
 24X  C21  H21   single    0.930  0.020  1.080
 24X  C21  C23   aromatic  1.392  0.020  1.392
 24X  C23  C26   aromatic  1.390  0.020  1.390
 24X  C23  C10   single    1.495  0.020  1.495
 24X  C26  H26   single    0.930  0.020  1.080
 24X  C26  C29   aromatic  1.389  0.020  1.389
 24X  C29  C9    single    1.519  0.020  1.519
 24X  C9   O2    deloc     1.251  0.020  1.251
 24X  C9   O1    deloc     1.241  0.020  1.241
 24X  C10  O4    double    1.225  0.020  1.225
 24X  C10  N3    single    1.344  0.020  1.344
 24X  N3   HN3   single    0.860  0.020  1.020
 24X  N3   C11   single    1.446  0.020  1.446
 24X  C11  H111  single    0.970  0.020  1.090
 24X  C11  H112  single    0.970  0.020  1.090
 24X  C11  C18   single    1.529  0.020  1.529
 24X  C18  H18   single    0.970  0.020  1.090
 24X  C18  C12   single    1.523  0.020  1.523
 24X  C18  C13   single    1.525  0.020  1.525
 24X  C12  H121  single    0.970  0.020  1.090
 24X  C12  H122  single    0.970  0.020  1.090
 24X  C12  H123  single    0.970  0.020  1.090
 24X  C13  H131  single    0.970  0.020  1.090
 24X  C13  H132  single    0.970  0.020  1.090
 24X  C13  H133  single    0.970  0.020  1.090
 24X  C14  N4    single    1.369  0.020  1.369
 24X  C14  N5    double    1.279  0.020  1.279
 24X  N4   HN41  single    0.890  0.020  1.040
 24X  N4   HN42  single    0.890  0.020  1.040
 24X  N5   HN5   single    0.890  0.020  1.040
 24X  C15  C19   aromatic  1.393  0.020  1.393
 24X  C15  H15   single    0.930  0.020  1.080
 24X  C15  C30   aromatic  1.387  0.020  1.387
 24X  C19  C22   aromatic  1.399  0.020  1.399
 24X  C19  C20   single    1.467  0.020  1.467
 24X  C22  C24   aromatic  1.384  0.020  1.384
 24X  C22  H22   single    0.930  0.020  1.080
 24X  C24  C27   aromatic  1.402  0.020  1.402
 24X  C27  C30   aromatic  1.387  0.020  1.387
 24X  C30  H30   single    0.930  0.020  1.080
 24X  C16  C20   double    1.332  0.020  1.332
 24X  C16  H161  single    0.930  0.020  1.080
 24X  C16  H162  single    0.930  0.020  1.080
 24X  C20  H20   single    0.930  0.020  1.080

loop_
_chem_comp_angle.comp_id
_chem_comp_angle.atom_id_1
_chem_comp_angle.atom_id_2
_chem_comp_angle.atom_id_3
_chem_comp_angle.value_angle
_chem_comp_angle.value_angle_esd
 24X  C6    N1   C2    118.96  3.000
 24X  H2    C2   C3    119.09  3.000
 24X  H2    C2   N1    116.13  3.000
 24X  C3    C2   N1    124.77  3.000
 24X  C14   C3   C4    123.53  3.000
 24X  C4    C3   C2    116.04  3.000
 24X  C14   C3   C2    120.43  3.000
 24X  H4    C4   C5    118.72  3.000
 24X  H4    C4   C3    120.82  3.000
 24X  C5    C4   C3    120.45  3.000
 24X  H5    C5   C6    121.37  3.000
 24X  H5    C5   C4    119.88  3.000
 24X  C6    C5   C4    118.75  3.000
 24X  N2    C6   C5    123.03  3.000
 24X  N2    C6   N1    115.95  3.000
 24X  C5    C6   N1    121.01  3.000
 24X  H72   C7   H71   106.29  3.000
 24X  H72   C7   C24   108.89  3.000
 24X  H71   C7   C24   109.46  3.000
 24X  C24   C7   N2    110.50  3.000
 24X  H72   C7   N2    110.02  3.000
 24X  H71   C7   N2    111.57  3.000
 24X  HN2   N2   C7    115.87  3.000
 24X  HN2   N2   C6    114.71  3.000
 24X  C7    N2   C6    123.29  3.000
 24X  C27   C8   C29   122.59  3.000
 24X  C29   C8   C17   119.20  3.000
 24X  C27   C8   C17   118.19  3.000
 24X  H17   C17  C21   119.18  3.000
 24X  C21   C17  C8    121.17  3.000
 24X  H17   C17  C8    119.65  3.000
 24X  H21   C21  C23   121.75  3.000
 24X  C23   C21  C17   120.01  3.000
 24X  H21   C21  C17   118.21  3.000
 24X  C10   C23  C26   118.08  3.000
 24X  C10   C23  C21   123.29  3.000
 24X  C26   C23  C21   118.62  3.000
 24X  H26   C26  C29   118.80  3.000
 24X  C29   C26  C23   121.89  3.000
 24X  H26   C26  C23   119.27  3.000
 24X  C9    C29  C26   118.43  3.000
 24X  C9    C29  C8    122.48  3.000
 24X  C26   C29  C8    119.01  3.000
 24X  O1    C9   O2    126.71  3.000
 24X  O1    C9   C29   116.81  3.000
 24X  O2    C9   C29   116.46  3.000
 24X  O4    C10  N3    122.71  3.000
 24X  N3    C10  C23   116.32  3.000
 24X  O4    C10  C23   120.96  3.000
 24X  HN3   N3   C11   117.04  3.000
 24X  C11   N3   C10   123.14  3.000
 24X  HN3   N3   C10   118.87  3.000
 24X  H112  C11  H111  106.87  3.000
 24X  H112  C11  C18   109.44  3.000
 24X  H111  C11  C18   110.14  3.000
 24X  C18   C11  N3    114.08  3.000
 24X  H112  C11  N3    107.66  3.000
 24X  H111  C11  N3    108.38  3.000
 24X  H18   C18  C13   108.82  3.000
 24X  C13   C18  C12   110.85  3.000
 24X  H18   C18  C12   108.06  3.000
 24X  C13   C18  C11   109.32  3.000
 24X  C12   C18  C11   111.41  3.000
 24X  H18   C18  C11   108.30  3.000
 24X  H123  C12  H122  106.72  3.000
 24X  H123  C12  H121  108.21  3.000
 24X  H122  C12  H121  107.88  3.000
 24X  H123  C12  C18   112.07  3.000
 24X  H122  C12  C18   110.92  3.000
 24X  H121  C12  C18   110.85  3.000
 24X  H133  C13  H132  107.57  3.000
 24X  H133  C13  H131  107.69  3.000
 24X  H132  C13  H131  107.47  3.000
 24X  H133  C13  C18   111.70  3.000
 24X  H132  C13  C18   111.08  3.000
 24X  H131  C13  C18   111.13  3.000
 24X  N5    C14  N4    125.64  3.000
 24X  N5    C14  C3    119.24  3.000
 24X  N4    C14  C3    115.08  3.000
 24X  HN42  N4   HN41  113.27  3.000
 24X  HN42  N4   C14   118.27  3.000
 24X  HN41  N4   C14   117.08  3.000
 24X  HN5   N5   C14   110.98  3.000
 24X  H15   C15  C30   119.51  3.000
 24X  C30   C15  C19   120.84  3.000
 24X  H15   C15  C19   119.65  3.000
 24X  C20   C19  C22   122.93  3.000
 24X  C20   C19  C15   119.17  3.000
 24X  C22   C19  C15   117.90  3.000
 24X  H22   C22  C24   118.47  3.000
 24X  H22   C22  C19   119.77  3.000
 24X  C24   C22  C19   121.75  3.000
 24X  C27   C24  C22   119.61  3.000
 24X  C27   C24  C7    120.04  3.000
 24X  C22   C24  C7    120.34  3.000
 24X  C30   C27  C24   119.04  3.000
 24X  C30   C27  C8    120.16  3.000
 24X  C24   C27  C8    120.76  3.000
 24X  H30   C30  C27   119.49  3.000
 24X  H30   C30  C15   119.65  3.000
 24X  C27   C30  C15   120.86  3.000
 24X  H162  C16  H161  116.35  3.000
 24X  H162  C16  C20   122.99  3.000
 24X  H161  C16  C20   120.66  3.000
 24X  H20   C20  C16   118.23  3.000
 24X  H20   C20  C19   114.83  3.000
 24X  C16   C20  C19   126.94  3.000

loop_
_chem_comp_tor.comp_id
_chem_comp_tor.id
_chem_comp_tor.atom_id_1
_chem_comp_tor.atom_id_2
_chem_comp_tor.atom_id_3
_chem_comp_tor.atom_id_4
_chem_comp_tor.value_angle
_chem_comp_tor.value_angle_esd
_chem_comp_tor.period
 24X  CONST_01  C4    C3   C2   N1      0.00   0.0  0
 24X  CONST_02  C4    C5   C6   N1      0.00   0.0  0
 24X  CONST_03  C5    C6   N1   C2      0.00   0.0  0
 24X  CONST_04  C5    C4   C3   C2      0.00   0.0  0
 24X  CONST_05  C6    N1   C2   C3      0.00   0.0  0
 24X  CONST_06  C6    C5   C4   C3      0.00   0.0  0
 24X  CONST_07  C22   C24  C27  C8    180.00   0.0  0
 24X  CONST_08  C15   C30  C27  C8    180.00   0.0  0
 24X  CONST_09  C23   C21  C17  C8      0.00   0.0  0
 24X  CONST_10  C23   C26  C29  C8      0.00   0.0  0
 24X  CONST_13  C26   C29  C8   C17     0.00   0.0  0
 24X  CONST_14  C26   C23  C21  C17     0.00   0.0  0
 24X  CONST_15  C27   C8   C17  C21   180.00   0.0  0
 24X  CONST_16  C29   C8   C17  C21     0.00   0.0  0
 24X  CONST_17  C29   C26  C23  C21     0.00   0.0  0
 24X  CONST_18  C27   C8   C29  C26   180.00   0.0  0
 24X  CONST_21  C24   C22  C19  C15     0.00   0.0  0
 24X  CONST_22  C24   C27  C30  C15     0.00   0.0  0
 24X  CONST_23  C27   C30  C15  C19     0.00   0.0  0
 24X  CONST_24  C27   C24  C22  C19     0.00   0.0  0
 24X  CONST_25  C30   C15  C19  C22     0.00   0.0  0
 24X  CONST_26  C30   C27  C24  C22     0.00   0.0  0
 24X  CONST_27  C14   C3   C2   N1    180.00   0.0  0
 24X  CONST_28  N2    C6   N1   C2    180.00   0.0  0
 24X  CONST_29  N2    C6   C5   C4    180.00   0.0  0
 24X  CONST_30  C14   C3   C4   C5    180.00   0.0  0
 24X  CONST_31  C19   C22  C24  C7    180.00   0.0  0
 24X  CONST_32  C8    C27  C24  C7      0.00   0.0  0
 24X  CONST_33  C30   C27  C24  C7    180.00   0.0  0
 24X  CONST_34  C9    C29  C8   C17   180.00   0.0  0
 24X  CONST_35  C10   C23  C21  C17   180.00   0.0  0
 24X  CONST_36  C9    C29  C26  C23   180.00   0.0  0
 24X  CONST_37  C10   C23  C26  C29   180.00   0.0  0
 24X  CONST_38  C27   C8   C29  C9      0.00   0.0  0
 24X  CONST_39  C20   C19  C22  C24   180.00   0.0  0
 24X  CONST_40  C20   C19  C15  C30   180.00   0.0  0
 24X  CONST_41  H5    C5   C6   N1    180.00   0.0  0
 24X  CONST_42  H4    C4   C3   C2    180.00   0.0  0
 24X  CONST_43  H2    C2   C3   C4    180.00   0.0  0
 24X  CONST_44  H30   C30  C27  C8      0.00   0.0  0
 24X  CONST_45  H21   C21  C17  C8    180.00   0.0  0
 24X  CONST_46  H26   C26  C29  C8    180.00   0.0  0
 24X  CONST_47  H17   C17  C21  C23   180.00   0.0  0
 24X  CONST_48  H22   C22  C19  C15   180.00   0.0  0
 24X  CONST_49  H15   C15  C19  C22   180.00   0.0  0
 24X  CONST_52  HN2   N2   C6   N1      0.00   0.0  0
 24X  CONST_53  C11   N3   C10  C23   180.00   0.0  0
 24X  CONST_54  HN3   N3   C10  C23     0.00   0.0  0
 24X  CONST_55  HN41  N4   C14  C3    180.00   0.0  0
 24X  CONST_57  HN5   N5   C14  C3    180.00   0.0  0
 24X  CONST_58  C11   N3   C10  O4      0.00   0.0  0
 24X  Var_01    N4    C14  C3   C2    157.19  30.0  2
 24X  Var_02    C24   C7   N2   C6   -142.01  30.0  2
 24X  Var_03    C22   C24  C7   N2   -121.97  30.0  2
 24X  Var_04    O2    C9   C29  C8     38.92  30.0  2
 24X  Var_05    O4    C10  C23  C21   159.33  30.0  2
 24X  Var_06    C16   C20  C19  C15   175.71  30.0  2
 24X  Var_07    H161  C16  C20  C19  -179.98   0.0  2
 24X  Var_08    C18   C11  N3   C10    90.08  30.0  3
 24X  Var_09    C12   C18  C11  N3     62.75  30.0  3
 24X  Var_10    H121  C12  C18  C11    58.55  30.0  3
 24X  Var_11    H131  C13  C18  C11   -63.56  30.0  3

loop_
_chem_comp_plane_atom.comp_id
_chem_comp_plane_atom.plane_id
_chem_comp_plane_atom.atom_id
_chem_comp_plane_atom.dist_esd
 24X  plan-1  N1    0.020
 24X  plan-1  C2    0.020
 24X  plan-1  C3    0.020
 24X  plan-1  C4    0.020
 24X  plan-1  C5    0.020
 24X  plan-1  C6    0.020
 24X  plan-1  N2    0.020
 24X  plan-1  C14   0.020
 24X  plan-1  H2    0.020
 24X  plan-1  H5    0.020
 24X  plan-1  H4    0.020
 24X  plan-2  C19   0.020
 24X  plan-2  C16   0.020
 24X  plan-2  H20   0.020
 24X  plan-2  H161  0.020
 24X  plan-2  H162  0.020
 24X  plan-2  C20   0.020
 24X  plan-3  C8    0.020
 24X  plan-3  C17   0.020
 24X  plan-3  C21   0.020
 24X  plan-3  C23   0.020
 24X  plan-3  C26   0.020
 24X  plan-3  C29   0.020
 24X  plan-3  C9    0.020
 24X  plan-3  C10   0.020
 24X  plan-3  C27   0.020
 24X  plan-3  H17   0.020
 24X  plan-3  H21   0.020
 24X  plan-3  H26   0.020
 24X  plan-4  C7    0.020
 24X  plan-4  C8    0.020
 24X  plan-4  C15   0.020
 24X  plan-4  C19   0.020
 24X  plan-4  C22   0.020
 24X  plan-4  C24   0.020
 24X  plan-4  C27   0.020
 24X  plan-4  C30   0.020
 24X  plan-4  H22   0.020
 24X  plan-4  H15   0.020
 24X  plan-4  H30   0.020
 24X  plan-4  C20   0.020
 24X  plan-5  C23   0.020
 24X  plan-5  C10   0.020
 24X  plan-5  N3    0.020
 24X  plan-5  O4    0.020
 24X  plan-5  C11   0.020
 24X  plan-5  HN3   0.020
 24X  plan-6  C6    0.020
 24X  plan-6  C7    0.020
 24X  plan-6  N2    0.020
 24X  plan-6  HN2   0.020
 24X  plan-7  C3    0.020
 24X  plan-7  C14   0.020
 24X  plan-7  N4    0.020
 24X  plan-7  N5    0.020
 24X  plan-7  HN41  0.020
 24X  plan-7  HN42  0.020
 24X  plan-7  HN5   0.020
 24X  plan-8  C29   0.020
 24X  plan-8  C9    0.020
 24X  plan-8  O2    0.020
 24X  plan-8  O1    0.020

